Single-phase laminates of iron titanate were formed by gelcasting in both the presence and absence of a magnetic field to produce alternating layers of textured and nontextured microstructure, respectively. X-ray analysis was performed on each lamina verifying that alignment was maintained throughout processing. Tunnel cracks were found in trilayer laminates (nontextured/textured/nontextured) when the alignment direction was parallel to the interface between layers. The cracks are consistent with a stress profile of residual tension parallel to the interface in the textured layer.
Crystallographically textured samples of iron titanate were produced by gelcasting in the presence of a strong magnetic field. Texture was assessed by measuring X-ray pole figures on samples that were cast in different orientations relative to the applied field. Specimens in this study exhibit fibertype texture, with the b-axes aligned parallel to the applied field. Peak texture strengths were on the order of 3 and 48 multiples of a random distribution (MRD) when processed in a 3.2 and 8.4 T magnetic field, respectively. This study shows that a combination of gelcasting with magnetic-fieldassisted processing provides a convenient method for fabricating samples which can be used to study the role of crystallographic texture on the physical properties of polycrystalline ceramics, e.g., their elastic or fracture behavior.
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