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Electron-stimulated desorption (ESD) of cryosorbed molecules on surfaces is a process of relevance to fields as varied as vacuum dynamics in accelerators and astrochemistry. While desorption from such molecular systems induced by keV electrons and fast ions has been extensively studied, the sub-keV electron regime is comparatively little known. We measured and quantified electron-stimulated desorption from molecular ice systems (layers of N2, CO, CO2, Ar, and H2O/D2O condensed at cryogenic temperatures) in the 150–2000 eV electron energy range. In this regime, stopping power is no longer sufficient to explain the electron energy dependence of ESD yields. We introduce the notion of desorption-relevant depth, which characterizes the transition between two energy deposition regimes near the surface. We then apply this notion to the different systems, showing how ESD in the sub-keV regime can, for example, reveal the differences in species diffusion in crystalline and porous amorphous CO2 ices.

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