Laser melting deposition (LMD) is a promising technology to produce net-shape parts. The deposited layers' characteristics and induced residual stress distribution influence the quality, mechanical, and physical properties of the manufactured parts. In this study, two theoretical models are presented. Initially, the clad geometry of the 1st deposited layer is estimated using the primary process parameters. Then, a hatch distance is used to calculate the re-melting depth and total clad geometry for all the deposited layers. The output of the 1st model is then used as an input in the 2nd model to estimate the residual stress distribution within the substrate and deposited layers. The model, for clad geometry, is validated using published experimental data for the depositions of AISI316L powder debits on AISI321 bulk substrate by the LMD process. For the residual stress distribution model validation, the published experimental results for X-ray diffractometry, in case of AISI4340 steel powder debits depositions on the AISI4140 bulk substrate by the LMD setup, are used. It was found that the current models can estimate the clad geometry and induced residual stress distribution with an accuracy of 10–15 % mean absolute deviation. An optimum selection of hatch distance is necessary for proper energy density utilization and dimensional control stability. The induced residual stress distribution was caused by the heating and cooling mechanisms, which appeared due to rapid heating and moderate cooling, in combination with slow conduction. These phenomena became incrementally iterative with the number of layers to be deposited, thus presenting a direct relationship between the residual stress distribution and the number of layers deposited on the substrate. The proposed models have high computational efficiency without restoring the meshing and iterative calculations. The high prediction accuracy and computational efficiency allow the presented model to investigate further the part distortion, part porosity, life-expectancy and mechanical properties of the part, and process parameter planning.
Powder flow and temperature distribution are recognized as essential factors in the laser melting deposition (LMD) process, which affect not only the layer formation but also its characteristics. In this study, two mathematical models were developed. Initially, the three-jet powder flow in the Gaussian shape was simulated for the LMD process. Next, the Gaussian powder flow was coaxially added along with the moving laser beam to investigate the effect of powder flow on temperature distribution at the substrate. The powder particles’ inflight and within melt-pool heating times were controlled to avoid vapors or plasma formation due to excessive heat. Computations were carried out via MATLAB software. A high-speed imaging camera was used to monitor the powder stream distribution, experimentally, while temperature distribution results were compared with finite element simulations and experimental analyses. A close correlation was observed among analytical computation, numerical simulations, and experimental results. An investigation was conducted to investigate the effect of the focal point position on powder stream distribution. It was found that the focal point position plays a key role in determining the shape of the powder stream, such that an increment in the distance from the focus point will gradually transform the powder stream from the Gaussian to Transition, and from the Transition to Annular streams. By raising the powder flow rate, the attenuation ratio prevails in the LMD process, hence, decreasing the laser energy density arriving at the substrate. The computations indicate that, if the particle’s heating temperature surpasses the boiling point, a strong possibility exists for vapors and plasma formation. Consequently, an excessive amount of laser energy is absorbed by the produced vapors and plasma, thus impeding the deposition process.
IV-VI semiconductor quantum dots embedded into an inorganic matrix represent nanostructured composite materials with potential application in temperature sensor systems. This study explores the optical, structural, and morphological properties of a novel PbS quantum dots (QDs)-doped inorganic thin film belonging to the Al2O3-SiO2-P2O5 system. The film was synthesized by the sol-gel method, spin coating technique, starting from a precursor solution deposited on a glass substrate in a multilayer process, followed by drying of each deposited layer. Crystalline PbS QDs embedded in the inorganic vitreous host matrix formed a nanocomposite material. Specific investigations such as X-ray diffraction (XRD), optical absorbance in the ultraviolet (UV)-visible (Vis)-near infrared (NIR) domain, NIR luminescence, Raman spectroscopy, scanning electron microscopy–energy dispersive X-ray (SEM-EDX), and atomic force microscopy (AFM) were used to obtain a comprehensive characterization of the deposited film. The dimensions of the PbS nanocrystallite phase were corroborated by XRD, SEM-EDX, and AFM results. The luminescence band from 1400 nm follows the luminescence peak of the precursor solution and that of the dopant solution. The emission of the PbS-doped film in the NIR domain is a premise for potential application in temperature sensing systems.
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