No abstract

Commercial heterogeneous solvent products (e.g., paints, inks and adhesives) were collected nationwide in Japan in 1980. The vapor phase of the product containers were analyzed for volatile organic solvent constituents by means of FID-gas chromatography on two FS-WCOT (OV-101 and PEG-600) capillary columns. Of 657 products collected (358 paints, 62 inks, 165 abhesives and 72 others), 136 samples were not analyzable because 75 gave numerous peaks (presumably containing gasoline) and others had no volatile component. Among the remaining 521 samples (298 paints, 52 inks, 120 achesives and 51 others), 70 gave only one peak while others gave multiple peaks, indicating the mixture of solvents rather than single solvent was commonly used. Of the organic solvent components identified, toluene was the most popular solvent throughout paints

No abstract

Personal monitoring of exposure to tetrachloroethylene (TETRA) with carbon felt dosimeters and analyses of urine for total trichloro-compounds (TTC) were carried out in two groups of workers (36 males and 25 females), one group (20 males and 19 females) in dry-cleaning workshops and the other (16 males and 6 females) engaged in the removal of glue from silk cloth. Comparison of the urinary TTC levels with TETRA in the environment revealed that, while the metabolite levels increased essentially linear to TETRA concentrations up to 100 ppm, leveling off was apparent in the metabolite excretion when the exposure to TETRA was more intense (e.g. more than 100 ppm), indicating that the capacity of humans to metabolize TETRA is rather limited, as previously discussed. From the set of the data thus obtained, screening levels of 30 and 61 mg TTC (as TCA)/l urine as the lower 95% confidence limits for a group mean were calculated for the biological monitoring, by means of urinalysis, of exposure to TETRA at 50 and 100 ppm (TWA), respectively. A tentative calculation with additional exhaled-air analyses indicated that, at the end of an 8-h shift with exposure to TETRA at 50 ppm (TWA), 38% of the TETRA absorbed through the lungs would be exhaled unchanged and less than 2% would be metabolized to be excreted into the urine, while the rest would remain in the body to be eliminated later.

No abstract