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Optical fibers with bismuth-doped silicate and germanate glass cores were fabricated by the modified chemical vapor deposition technique (solution and vapor-phase Bi incorporation). The fibers revealed an efficient luminescence with a maximum in the 1050-1200 nm spectral range, FWHM up to 200 nm, and a lifetime of the order of 1 ms.

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The generation of 236 mW of second-harmonic power in a 32-cm-long periodically poled silica fiber, corresponding to an average conversion efficiency of 15.2+/-0.5%, is reported. This represents the highest normalized second-harmonic conversion and the highest average second-harmonic power ever reported for a periodically poled silica fiber, to our knowledge. The enhancement is attributed to an improved design of the specialty twin-hole fiber and the extension of the nonlinear interaction length.

Heavily Er-doped fibers (EDFs) based on P(2)O(5)-Al(2)O(3)-SiO(2) (PAS) ternary glass have been studied. A unique feature of this glass is the formation of a AlPO(4) join having a structure similar to that of SiO(2) glass and a refractive index below it. It is found that the Er(3+) absorption and emission spectra in the PAS EDFs are defined by the dopant (Al(2)O(3) or P(2)O(5)) present in excess and are close to those of the corresponding binary glass (Al(2)O(3)-SiO(2) or P(2)O(5)-SiO(2)). The presence of the AlPO(4) join results in the enhancement of the pump-to-signal conversion efficiency in the PAS EDFs as compared with the EDFs based on the P(2)O(5)-SiO(2) and Al(2)O(3)-SiO(2) (with 1.5 mol. %Al(2)O(3) and less) binary glasses. The PAS host glass is advantageous in the case of large-mode-area active fibers.