Soft neural electrode arrays that are mechanically matched between neural tissues and electrodes offer valuable opportunities for the development of disease diagnose and brain computer interface systems. Here, a thermal release transfer printing method for fabrication of stretchable bioelectronics, such as soft neural electrode arrays, is presented. Due to the large, switchable and irreversible change in adhesion strength of thermal release tape, a low‐cost, easy‐to‐operate, and temperature‐controlled transfer printing process can be achieved. The mechanism of this method is analyzed by experiments and fracture‐mechanics models. Using the thermal release transfer printing method, a stretchable neural electrode array is fabricated by a sacrificial‐layer‐free process. The ability of the as‐fabricated electrode array to conform different curvilinear surfaces is confirmed by experimental and theoretical studies. High‐quality electrocorticography signals of anesthetized rat are collected with the as‐fabricated electrode array, which proves good conformal interface between the electrodes and dura mater. The application of the as‐fabricated electrode array on detecting the steady‐state visual evoked potentials research is also demonstrated by in vivo experiments and the results are compared with those detected by stainless‐steel screw electrodes.
Blue-emitting
heavy-metal free QDs simultaneously exhibiting photoluminescence
quantum yield close to unity and narrow emission line widths are essential
for next-generation electroluminescence displays, yet their synthesis
is highly challenging. Herein, we develop the synthesis of blue-emitting
QDs by growing a thin shell of ZnS on ZnSe cores with their size larger
than bulk Bohr diameter. The bulk-like size of ZnSe cores enables
the emission to locate in the blue region with a narrow emission width
close to its intrinsic peak width. The obtained bulk-like ZnSe/ZnS
core/shell QDs display high quantum yield of 95% and extremely narrow
emission width of ∼9.6 nm. Moreover, the bulk-like size of
ZnSe cores reduces the energy level difference between QDs and adjacent
layers in LEDs and improves charge transport. The LEDs fabricated
with these high-quality QDs show bright pure blue emission with an
external quantum efficiency of 12.2% and a relatively long operating
lifetime.
Vanadium dioxide (VO2) with its unique sharp resistivity change at the metal-insulator transition (MIT) has been extensively considered for the near-future terahertz/infrared devices and energy harvesting systems. Controlling the epitaxial quality and microstructures of vanadium dioxide thin films and understanding the metal-insulator transition behaviors are therefore critical to novel device development. The metal-insulator transition behaviors of the epitaxial vanadium dioxide thin films deposited on Al2O3 (0001) substrates were systematically studied by characterizing the temperature dependency of both Raman spectrum and Fourier transform infrared spectroscopy. Our findings on the correlation between the nucleation dynamics of intermediate monoclinic (M2) phase with microstructures will open a new avenue for the design and integration of advanced heterostructures with controllable multifunctionalities for sensing and imaging system applications.
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