A series of beta-formyl-BODIPYs 2 were synthesized in high yields from tetramethyl-BODIPYs 1 via the Vilsmeier-Haack reaction and were further functionalized using a Knoevenagel condensation to generate novel BODIPYs 3 and 4.
He completed his bachelor of science in agriculture and the master in agricultural extension education from Bangladesh Agricultural University. He also completed MBA from commonwealth of learning. He also completed two diplomas in banking and Islamic banking. His research interest includes resilience, disaster management, livelihood and climate changes and education economy. He has published couple of scientific articles and one book on Poverty of Island Char Dwellers in Bangladesh. He is a member of several professional bodies. Mr. Sarker is now working as an editorial board member of several social sciences and public administration journals.
An
efficient and practical Rh(III)-catalyzed redox-neutral [4 +
1] annulation of N-phenoxy amides with α,α-difluoromethylene alkynes has been realized
to give direct access to the Z-configured monofluoroalkenyl
dihydrobenzo[d]isoxazole framework with broad substrate
compatibility and good functional group tolerance, which was further
enhanced by the late-stage C–H modification of complex bioactive
compounds. Subsequent density functional theory calculations revealed
that the stereoselective β–F elimination involving an
allene species played a decisive role in determining the reaction
outcome and such Z-selectivity.
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