To realize the high efficiency organic photovoltaics (OPVs), two critical requirements have to be fulfilled: (1) increasing the photon energy absorption range of the active layer, and (2) improving charge separation and transport in the active layer. This study reports the utilization of THC8, a novel fluorescence-based polymer containing propeller-shaped di-triarylamine and fluorene moieties in the active layer consisting of poly-3-hexylthiophene and [6,6]-phenyl-C61-butyric acid methyl ester to form a ternary bulk heterojunction. The results showed that the high absorbance and strong fluorescence of THC8 at 420 and 510 nm, respectively, broadened the spectral absorption of the OPV, possibly through Förster resonance energy transfer. In addition, the morphology of the device active layer was improved with the addition of a suitable amount of THC8. Consequently, the charge transport property of the active layer was improved. The best power conversion efficiency (PCE) of the device with THC8 was 3.88%, a 25% increase compared to the PCE of a pristine OPV.

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The aim of this study was to investigate the effect of gold nanoparticle (Au NP)-induced surface plasmons on the performance of organic photovoltaics (OPVs) that consist of copper phthalocyanine and fullerene as the active materials. The photon absorption can be enhanced by immobilization of surfactant-stabilized Au NPs on a self-assembled monolayer-modified indium tin oxide (ITO) electrode, and thus, the photocurrent as well as the power conversion efficiency (PCE) of these OPVs can be improved. Varying the density of the immobilized Au NPs in the devices provided no significant variation in the charge mobility but it did enhance the photocurrent. In addition, device simulation results demonstrated that the improvement in photocurrent was due to the enhancement of light absorption and the increase in charge separation, which was facilitated by the Au NPs. Overall, we attributed the improvement in PCE of OPVs to a localized surface plasmon resonance effect generated by the Au NPs.

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