No abstract

Human health and industrial instruments have been suffering from bacterial colonization on the surface of materials for a long time. Recently, antibacterial coatings are regarded as the new strategy to resist bacterial pathogens. In this work, novel highly transparent and superhydrophobic coatings with extremely low bacterial adhesion and bactericidal performance were prepared by spray-coating hydrophobic silica sol and CuO nanoparticles. The coated glass showed high transmittance in 300-2500 nm with a maximum value of 96.6%. Compared with bare glass, its superhydrophobic characteristics resulted in a reduction in adhesion of bacteria ( Escherichia coli, E. coli) by up to 3.2 log cells/cm. Additionally, the live/dead staining test indicated that the as-prepared coating exhibited excellent bactericidal performance against E. coli. Moreover, the as-prepared coating could maintain their superhydrophobicity after the sand impact test. The proposed method to fabricate such coatings could be applied on various substrates. Therefore, this novel hybrid surface with the abilities to reduce bacterial adhesion and kill attached bacteria make it a promising candidate for biosensors, microfluidics, bio-optical devices, household facilities, lab-on-chips, and touchscreen devices.

In this work, quartz crystal microbalance (QCM) sensors for detection of trace hydrogen cyanide (HCN) gas were developed based on nanostructural (flower-like, boat-like, ellipsoid-like, plate-like) CuO. Responses of all the sensors to HCN were found to be in an opposite direction as compared with other common volatile substances, offering excellent selectivity for HCN detection. The sensitivity of these sensors is dependent on the morphology of CuO nanostructures, among which the plate-like CuO has the highest sensitivity (2.26 Hz/μg). Comparison of the specific surface areas of CuO nanostructures shows that CuO of higher surface area (9.3 m(2)/g) is more sensitive than that of lower surface area (1.5 m(2)/g), indicating that the specific surface area of these CuO nanostructures plays an important role in the sensitivity of related sensors. On the basis of experimental results, a sensing mechanism was proposed in which a surface redox reaction occurs between CuO and Cu(2)O on the CuO nanostructures reversibly upon contact with HCN and air, respectively. The CuO-functionalized QCM sensors are considered to be a promising candidate for trace HCN gas detection in practical applications.