A series of novel energetic salts of 2,4,6-trinitropyridin-3-ol have been prepared and confirmed structurally. These compounds can be prepared by means of a facile synthetic procedure and show outstanding properties (detonation velocity, detonation pressure, sensitivity toward mechanical stimuli, and temperature of decomposition). They were isolated and characterized by means of elemental analysis, multinuclear (1 H, 13 C) NMR spectro-scopy. The structures in the crystalline state were determined by single-crystal X-ray diffraction at 296 K. From the calculated standard molar enthalpy of formation (CBS-4 M) and the densities, the Chapman-Jouguet detonation properties were predicted by using the EXPLO5 V6.02 thermochemical computer code. Their sensitivities towards impact and friction were also determined.
<abstract><p>The road network system is the core foundation of a city. Extracting road information from remote sensing images has become an important research direction in the current traffic information industry. The efficient residual factorized convolutional neural network (ERFNet) is a residual convolutional neural network with good application value in the field of biological information, but it has a weak effect on urban road network extraction. To solve this problem, we developed a road network extraction method for remote sensing images by using an improved ERFNet network. First, the design of the network structure is based on an ERFNet; we added the DoubleConv module and increased the number of dilated convolution operations to build the road network extraction model. Second, in the training process, the strategy of dynamically setting the learning rate is adopted and combined with batch normalization and dropout methods to avoid overfitting and enhance the generalization ability of the model. Finally, the morphological filtering method is used to eliminate the image noise, and the ultimate extraction result of the road network is obtained. The experimental results show that the method proposed in this paper has an average F1 score of 93.37% for five test images, which is superior to the ERFNet (91.31%) and U-net (87.34%). The average value of IoU is 77.35%, which is also better than ERFNet (71.08%) and U-net (65.64%).</p></abstract>
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