With the improvement of medical and health care level in our society, the demand for antibacterial materials is increasing. In this work, we prepared the antibacterial materials by loading silver nanoparticles (AgNPs) on the dialdehyde cellulose (DAC) with in-situ synthesis method. DAC was prepared by pretreating cellulose fiber with sodium metaperiodate (NaIO 4 ) to convert the hydroxyl group into aldehyde group, and then reacted with silver nitrate (AgNO 3 ) to obtain AgNPs loaded on DAC. UV–Vis results show that the characteristic absorption peak of AgNPs at 428 nm appeared in the AgNPs-loaded-DAC. It was observed by SEM that the spherical AgNPs were distributed uniformly on the DAC surface without obvious flocculation. The color of DAC was not changed significantly, indicating that a small amount of AgNPs was loaded. In addition, sodium citrate (Na 3 C 6 H 5 O 7 ) was added in the reaction of DAC and AgNO 3 and its effect on the formation of AgNPs was studied. The results demonstrated that the color of DAC turned deeper and finally dark yellow with reaction time extended. When the reaction time was 60 h, the spherical AgNPs were gradually grown and transformed into triangular prism on the DAC surface. The antibacterial properties of AgNPs showed inhibition zones of 4.90 mm and 7.35 mm (60 h) against Gram-negative ( E. coli ) and Gram-positive ( S. aureus ), respectively, which increased by 40.00% and 14.85% compared with spherical AgNPs (2.5 h) obtained without Na 3 C 6 H 5 O 7 . The research of AgNPs-loaded cellulose-based materials promotes the development prospect of new nano-antibacterial materials. Graphical abstract Supplementary Information The online version contains supplementary material available at 10.1007/s10570-022-04692-6.
In this study, the effect of the alkyl chain of quaternary ammonium cationic surfactants on corrosion inhibition in hydrochloric acid (HCl) solution was investigated by using dodecyl trimethyl ammonium chloride (DTAC), tetradecyl trimethyl ammonium chloride (TTAC), cetyl trimethyl ammonium chloride (CTAC), and octadecyl trimethyl ammonium chloride (OTAC) as corrosion inhibitors to uncover their structureeefficiency relationships. The effect of the alkyl chain of quaternary ammonium cationic surfactants on corrosion inhibition in HCl solution was studied under different conditions, such as corrosion inhibitor concentration, temperature, and acidity, and this was done using the weightlessness method. The results obtained show that these inhibitors have high corrosion inhibition effect on A 3 steel, and the corrosion inhibition efficiency is dependent on the length of the alkyl chain. At the same concentration, the longer the alkyl chain, the weaker the corrosion inhibition effect. When the temperature was 50 C and the concentration of corrosion inhibitor was 70 mg/L, the corrosion inhibition efficiency order of the four cationic surfactants was DTAC > TTAC > CTAC > OTAC. Besides, the experimental results obtained show that the adsorption of the inhibitor on the A 3 steel surface conforms to the Langmuir type isotherm, and then the corresponding adsorption thermodynamic parameters were obtained according to these parameters. It was observed that DH, DS, and E a increased with increase in the length of the alkyl chain. The adsorption of the inhibitor on the steel surface is an exothermic, spontaneous, entropy process.
In this study, a viscoelastic surfactant gel was composed using erucoylamine propyl betaine and other additives. The formulation of this viscoelastic surfactant gel solution was determined as: erucamide propyl betaine:oleic acid amide propyl betaine:octadecyl hydroxyl sulfonate betaine = 1.7%:1.36%:0.01%. Then the performance of viscoelastic surfactant gel fluid was evaluated. The results showed that the viscoelastic surfactant gel has good temperature resistance and salt resistance. At 50°C, the apparent viscosity reaches the maximum value, 37 mPa · s, and it displays high shear resistance under the shear rate of 170 s–1, with the viscosity retention of 83.3%. Kerosene (1%) can completely break the gel within 2 h, which can convert the gel into a surfactant solution soon. Also the gel shows high emulsion ability, which can benefit the oil displacement in oilfield. Finally this gel can enhance the oil displacement rate as high as 28%.
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