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A strong long-range transported (LRT) fine particle (PM 2:5 ) episode occurred from March 17-22, 2002 over large areas of Finland. Most of the LRT particle mass was in the submicrometre size fraction. The number of concentrations of 90-500 nm particles increased by a factor of 5.6 during the episode, but the concentrations of particles smaller than 90 nm decreased. This reduction of the smallest particles was caused by suppressed gas-to-particle conversion due to the vapour uptake of LRT particles. Individual particle analyses using SEM/EDX showed that the proportion of sulphurrich particles rose strongly during the episode and that the relative weight percentage of potassium was unusually high in these particles. The median S/K ratios of S-rich particles were 2.1 at the beginning of the episode, 5.2 at the peak stage of the episode and 8.9 during the reference days. The high proportion of K is a clear indication of emissions from biomass burning, because K is a good tracer of biomass-burning aerosols. Trajectories and satellite detections of fire areas indicated that the main source of biomass-burning aerosols was large-scale agricultural field burning in the Baltic countries, Belarus, Ukraine and Russia. The higher S/K ratio of S-rich particles during the peak stage was obviously due to the increased proportion of fossil fuel-burning emissions in the LRT particle mass, since air masses arrived from the more polluted areas of Europe at that time. The concentrations of sulphate, total nitrate and total ammonium increased during the episode. Our results suggest that large-scale agricultural field burning may substantially affect PM 2:5 concentrations under unfavourable meteorological conditions even at distances over 1000 km from the burning areas. r

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