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This project aimed to study the reinforcement effect of fungal chitin at different loading on chitin/PLA composite. The chitin nanofibers were extracted from three mushroom species (oyster mushroom Pleurotus ostreatus, shiitake mushroom Lentinula edodes, enoki mushroom Flammulina velutipes) and used as a reinforcement element in PLA. The chitin/PLA composite was fabricated using a solvent-casting method followed by the hot-compress molding method. In the solvent-casting method, the chitin nanofibers were dispersed in PLA/chloroform mixture and the mixture was left for solvent evaporation. The solvent-free chitin/PLA thin film was then filled in dog bone mold before proceeded with hot-compress molding at 190°C and 70 bar. The samples with different chitin loading were tested with tensile test to study the mechanical performance of nanocomposite. The chitin/PLA composite from oyster mushroom shows the optimum result (σ= 43 MPa, E= 12 MPa) at 5% chitin loading. The increment of the chitin loading leads to a decrease in both strength and strain. However, for the samples from enoki and shitake mushrooms, the optimum chitin loading is 10% with 55 MPa and 56 MPa tensile strength, respectively. This study suggests the potential of fungal chitin as reinforcement in PLA.

The influence of the pre-treatment process (freezing, drying) on the tensile properties of chitin paper obtained from nanofibers of three commercial species of fungi: oyster mushrooms (P. ostreatus), enoki (F. velutipes) and shiitake (L. edodes) was investigated. The chitin nanofibers were extracted by a mild alkaline process. The highest tensile strength was observed for paper obtained from fresh mushrooms fibers, which may result from the lack of the chitin fiber modification. Freezing and drying processes have been found to reduce the strength of the paper, possibly due to ice crystal formation and the keratinization effect of the nanofibers, respectively. The paper obtained from enoki fungus nanofibers was characterized by the highest tensile strength, which may be due to the very long fiber. However, in terms of elongation at break, the best results were obtained with oyster mushrooms nanofibers, probably due to the relatively shorter chitin fiber. The long enoki nanofibers can therefore be used as a good reinforcement of the paper.

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