The utilization of less expensive and more effective adsorbents derived from a variety of basic materials has been investigated. The research aimed to investigate the feasibility of employing waste paper as the adsorbent to remove the cresol red (CR) dye from wastewater through adsorption mechanism. Langmuir, Jovanovic, and Freundlich model were observed for isotherms models, while pseudo-first-order and pseudo-second-order were examined for kinetic models. The results indicated that increasing the adsorbent dose and contact time gave no significant effect to adsorption capacity while adsorption capacity increased with the increasing of pH until it reached a maximum at pH 8, and raising the starting dye concentration leads in a significant increase in adsorption capacity (16.7 mg/g). When the experimental adsorption isotherms and kinetic were fitted using the Freundlich models and pseudo-second-order model, it was discovered that those models were more accurately represented by the data, as indicated by a high correlation coefficient (R2) of 0.974 and 0.963.
Summary
Unconventional plays pose a challenging set of operational conditions, including high temperature, high salinity, low permeability, and fracture networks. Aggressive development of these plays and the low primary recovery factors present an opportunity for using enhanced oil recovery (EOR) methods. This work presents a laboratory investigation of miscible ethane (C2H6) foam for gas EOR conformance in low-permeability, heterogeneous, harsh environments [<15 md, 136,000 ppm total dissolved solids (TDS) with divalent ions, 165°F]. The use of C2H6 as an alternative to carbon dioxide (CO2) offers several operational and availability strengths, which might expand gas EOR applications to depleted or shallower wells. Coupling gas conformance also helps improve displacement efficiencies and maximize overall recovery. Minimum miscibility pressure (MMP) displacement tests were performed for dead crude oil from the Wolfcamp Spraberry Trend area using C2H6 and CO2. Aqueous stability, salinity scan, and static foam tests were performed to identify a formulation. Subsequent foam quality and coreflood displacement tests in heterogeneous carbonate outcrop cores were conducted to compare the recovery efficiencies of three processes: gravity-unstable, miscible C2H6 foam; gravity-stable, miscible C2H6; and gravity-unstable, miscible C2H6 processes. Slimtube tests comparing C2H6 to CO2 resulted in a lower MMP value for C2H6. We identified a stable surfactant blend capable of Type I microemulsion and persistent foams in the presence of oil. Corefloods conducted with gravity-unstable miscible C2H6 foam, gravity-stable miscible C2H6, and gravity-unstable miscible C2H6 recovered 98.4, 61.9, and 42.6% oil originally in place, respectively. Our work shows that miscible C2H6 injection processes achieved significant recoveries even under gravity-unstable conditions. The addition of foam provides better conformance control, enhancing overall recovery at the laboratory scale, showing promise for field applications.
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