The pH of fish muscle is an important index for quality assessment, but the traditional methods using a pH meter and probe/electrode are destructive, time-consuming, and laborious, making them unsuitable for on-line meat-quality monitoring. Hence, an approach of using fluorescence fingerprints (FFs) for the non-destructive prediction of pH in frozen fish fillets was trialled. Sixty-three live horse mackerel (Trachurus japonicus) and spotted mackerel (Scomber australasicus) were freshly harvested, sacrificed instantly, then preserved in ice, filleted, vacuum-packed, and frozen. Subsequently, the FFs of all frozen fillets were recorded using a fibreoptic-equipped fluorescence spectrometer, and the corresponding pH values of the samples were measured. After pre-processing, the masked FFs were modelled using partial least squares regression (PLSR) for the prediction of pH values. The results revealed that the developed method was accurate enough for predicting the pH changes in frozen horse mackerel and spotted mackerel fillets with R2 = 0.71 and R2 = 0.90, respectively. The proposed technique could be utilized as a rapid and non-contact alternative to traditional pH electrodes for the quality monitoring of fish products.
Countless marine organisms were polluted with radioactive materials that were dispersed when the Fukushima Daiichi Nuclear Power Plant (FDNPP) was damaged in 2011 by the Great East Japan Earthquake. The aim of this study was to determine the degree to which marine herbivorous sea urchins, Mesocentrotus nudus, were contaminated with radiocesium because of the accident. We collected samples of sea urchins from four locations in Fukushima prefecture (at the coast and offshore from the Yotsukura and Ena stations) and investigated how the 137Cs activity concentrations changed. The biological half-life (Tbio) of 137Cs in the individual sea urchins was between 121 and 157 days. The ecological half-life (Teco) of 137Cs was 181–423 days and was high in places close to the FDNPP. The Teco values in the sea urchins were longer than previously reported. The results infer that the food sources of the sea urchins around the Fukushima coast strongly influenced their uptake of 137Cs.
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