Metallic colloids are frequently used in industry and provide understanding of science at microns to nanometers scales along with their applicability for various technologically important applications. Present investigations deal morphology-structure of gold, silver and their binary composition while processing the certain amount of their solutions in a newly designed process and tap opportunities of developing tiny shaped particles. At tuned ratio of pulse OFF to ON time and when gold solution was processed, several tiny shaped particles developed at solution surface. Such tiny particles deal force at the tip of each converted structure of smooth element under the steady-state immersing behavior pointing toward common centre to pack for developing different geometric anisotropic shaped particles. Under identical parameters along with pulse time, processing solutions of silver nitrate and binary composition of chloroauric acid-silver nitrate result into develop tiny particles having no specific shape where their packing deal mixed behavior of force resulting into develop distorted particles.Elongation and deformation of gold and silver atoms while in different structures is because of the plastically-driven behavior of electrons as per stretching of their clamped energy knots. In structure of three-dimensional where electrons of atoms do not deal transition require for elongation they retain the structure as it is known in hcp structure or two-dimensional structure. Different nature of precursors along with morphologystructure of particles is discussed in this paper opening abundant avenues of research.

Tiny-sized particles under the scheme of monolayer assembly, comprising gold atoms, developed at a different processing time in a pulse-based process. For a different processing time, atoms bind into different tiny particles under the placing packets of nanoshape energy where they elongate as per arrangement and when in one-dimensional arrays, they convert into structures of smooth elements. For different processing time and where tiny particles possess triangular-shape, they pack to develop extended shapes where development rate of an anisotropic particle is not more than millisecond time. Increasing the processing time of solution upto certain duration increases the number of developing tiny particles in a triangular-shape, so, their extended shapes also. Uniformly adjacent-orientation of electrons in atoms of tinyshaped particle is because of exerting uniform surface force along their opposite poles as per gained potential energy where stretching of their clamped energy knots is remained orientational-based. At a different processing time, inter-spacing distance of spotted intensity spots in selective area photons reflection patterns of particles is remained the same as for the case of their structures of smooth elements visualized through transmission microscope high-resolution images. When the forceful coinciding of two parallel structures of smooth elements is occurred, they bind into single element structure (of smooth element) by a bit overlying inner sides, thus, giving its double width where certain filled state electrons and unfilled energy knots (belonging to sides of elongated atoms of parallel structures of smooth elements) coordinate to adhere. This 2 study discusses the formation of tiny particles following by their extended shapes at different processing time of gold solution while employing a pulse-based electronphoton solution-interface process where they become the origin of physics and chemistry of materials by discussing many commonly-known phenomena and processes, so, opening the alternative routes to design materials and explore science.

Carbon is one of the most investigated materials and shows chaotic behavior in terms of evolving structure. Synthesizing carbon materials largely depend on the deposition technique, process parameters, condition of substrate surface and ratio of the gaseous chemistry. A variety of techniques have been employed to depositing carbon films from various gaseous mixtures to different substrate materials.In this study, carbon thin and thick films are discussed for different techniques known as hot filament chemical vapor deposition and microwave plasma chemical vapor deposition where their synthesis process has been explained in a new context. Here, we discuss attained dynamics of atoms (or their tiny grains) amalgamating into a particular phase of grain or crystallite and electron-dynamics responsible for binding atoms in the formation of all sorts of tiny grains, grains and crystallites controlling overall morphology-structure of films thickness at few nanometers to several microns. Carbon atoms when in solid state, on amalgamation at flat surface result into bind under uniform electron-dynamics and when the amalgamation is at uneven surface, (even at atomic level) they result into bind under non-uniform electron-dynamics. Where binding of atoms is at uniform electron-dynamics, a graphitic structure evolves following by different modifications into other carbon phases depending on the orientation of electron Modified Final Version 2 states with respect to centre of inner part of atom known as nucleus. Substrates under appropriate surface defects or abrasion result into an improved rate of nucleation of tiny grains, hence, their increased rate of growth. This study embarks on unexplored science of carbon films where in addition to localized process parameters nature of substrate also influence dynamics of formation of tiny clusters, grains and crystallites at their initial stage of formation. Our results and discussions enlighten us to revisit the nucleation and growth mechanisms of different sorts of films deposit at any scale and at any substrate surface constituting different composition.

Different peak trends of tiny grains carbon film have been observed under the investigations of the Raman spectroscopy and energy loss spectroscopy. Carbon films known in nanocrystalline and ultrananocrystalline diamond films are synthesized by employing microwave-based vapor deposition system. Carbon atoms exhibit several state behaviors depending on the incurred positions of their electrons. Different morphology of tiny grains under different chamber pressure is related to different rate of arriving typical energies at/near substrate surface. Those tiny grains of carbon film, which evolved in graphitic state atoms are converted to structure of smooth elements where elongation of atoms of one-dimensional arrays is as per exerting surface format forces along opposite poles from their centers. Such tiny grains in the film are the cause of v 1 peak under the investigation of the Raman spectrum because of the enhanced propagation of input laser signals through channelized inter-state electron gaps of elongated graphitic state atoms. Those tiny grains of carbon film, which evolved in fullerene state are the cause of v 2 peak. The tiny grains related to v 1 peak possess a low intensity as compared with the ones which comprised atoms having state behaviors known in their exceptional hardness. Tiny grains representing v 1 peakin the Raman spectrum are also the cause of field emission characteristic of a carbon film. Different peak recordings were made for the Raman at defined positions indicating a different state of carbon atoms for a different phase of deposited tiny grains, which is in line to their energy loss spectroscopy.

Many studies deal synthesis of carbon because of its versatility but lack the arresting of understanding at convincing and compelling levels. A binding energy shape-like parabola is linked to state of handing over electron to state of taking over electron at each opposite side of the atom maintaining the equilibrium of resulting new state of the carbon atom. Through this mechanism of transferring electrons for the gas state carbon atom, it converts into graphitic state, nanotube state, fullerene state, diamond state, lonsdaleite state and graphene state carbon atom. Forces of relevant poles remain neutral at instant of transferring electrons to attain specific state of their carbon atom. Structure evolutions in graphitic, nanotube and fullerene state carbon atoms are remained one-dimensional, two-dimensional and four-dimensional, respectively, where energy shape-like parabola is also involved along the relevant quadrant executing electron-dynamics to engage neutral behavior of exerting relevant poles forces. A graphite structure when develops under attained dynamics of atoms and their binding is under a bit difference of involved opposite pole forces, it develops in two-dimensional also. Evolution of structure in diamond, lonsdaleite and graphene state carbon atoms is under involving potential energy of electrons dealing double clamping of energy knot where relevant poles forces exerted in the orientationally controlled manner. Growth of diamond is south to ground, but binding of atoms is ground to south, so, it is a tetra-electrons ground to south topological structure. Lonsdaleite is a bi-electrons ground to just-south topological structure. Growth of graphene is just-north to ground, but binding of atoms is ground to just-north, so, it is a tetra-electrons ground to just-north topological structure. Glassy carbon is related to a layered-topological structure where successive tri-layers of gas, graphitic and lonsdaleite state atoms bind in the repetition manner. In glassy carbon, pairs of orientated electrons of gas and lonsdaleite state carbon atoms deal double clamping of energy knot by entering from the rear-side and front-side, respectively, to bind to intermediate layers of graphitic state atoms. Different carbon atoms develop amorphous structures when they bind under frustrating amalgamation. Hardness of carbon-based materials is also sketched in the light of different force-energy behaviors of different state carbon atoms. Here, structure evolution in each carbon state atom explores its own science.