There is escalating salinity levels on small islands due to uncontrolled groundwater extraction. Conventionally, this challenge is addressed by adopting optimal groundwater pumping strategies. Currently, on Unguja Island (Zanzibar), urban freshwater is supplied by desalination, which is expensive and energy-intensive. Hence, desalinization cannot be afforded by rural communities. This study demonstrates that the innovative Kilimanjaro Concept (KC), based on rainwater harvesting (RWH) can remediate seawater intrusion in Unguja, while enabling a universal safe drinking water supply. The reasoning is rooted in the water balance of the whole island. It is shown that if rainwater is systematically harvested, quantitatively stored, and partly infiltrated, seawater intrusion will be reversed, and a universal safe drinking water supply will be secured. Water treatment with affordable technologies (e.g., filtration and adsorption) is suggested. The universality of KC and its suitability for small islands is demonstrated. Future research should focus on pilot testing of this concept on Unguja Island and other island nations.

Biosorbents are found promising for the detoxification of water contaminants. This comprehensive review indicates that these biosorbents are more efficient and cost-effective for the purification of water and wastewater containing lead(ii) ions.

This study investigated the levels of Pb, Hg, Cr, Cd, and As in water and sediments from the tributaries of the Mara River, Tanzania. Pollution risk of water and sediments was investigated using seven indices and five metals. During the dry period, the highest concentration of Pb, Hg, Cr, Cd, and As in sediments was 17.45 ± 1.22, 0.01, 1.56 ± 0.5, 1.3 ± 0.09, and 30.81 ± 0.02 mg/kg, respectively. During the wet period, the highest concentration of Pb, Hg, Cr, Cd, and As in sediments was 4.37 ± 0.28, 0.012, 2.58 ± 0.57, 2.25 ± 0.35, and 53 ± 0.02 mg/kg, respectively. For surface water, the respective highest concentrations of Pb, Hg, Cr, Cd, and As were 0.76 ± 0.09, 0.04, 0.68 ± 0.09, 0.74 ± 0.1, and 0.47 ± 0.06 mg/L for the dry period. The wet period max concentrations for Pb, Hg, Cr, Cd, and As in surface water were 0.56, 0.03, 0.55 ± 0.03, 0.48 ± 0.03, and 0.4 ± 0.03 mg/L, respectively. Principal component analysis results indicated dominant loadings for Pb and As in sediments during the dry period. Comparison of sediment concentrations with sediment quality guidelines revealed that As and Cd were enriched. Correlation coefficient results indicated that As had a strong negative correlation with the rest of the elements in sediments during the dry period. In the wet period, As had a significant correlation with Cd (r = 0.92, p < 0.01) in sediments. The analysis of environmental risks indicated significant enrichment of sediments with As and Cd. It is important to put in place relevant control mechanisms targeting metals in the studied tributaries, with a focus on As and Cd.

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