Fundamental research has extensively described the various biological and medical effects of consuming the microalgae spirulina or its constituents. A number of studies indicate an increase in the immune response when they are used for the manifestation of anti-inflammatory, antidiabetic and other important properties. The composition of spirulina and its biological effects make it a unique dietary supplement, the inclusion of which in food products will provide them with functional properties. It has been proven that spirulina has a number of important functional and technological properties for its use as a component in recipes for meat products. In the study of the functional and technological properties of spirulina, it was found that the water absorption capacity was 117.8%, fat absorption was 117.0% and the swelling degree was 177.6%. At the same time, spirulina had low emulsifying and gelling properties. The introduction of spirulina paste into the recipe in a dosage of 1 to 2.5% can increase the quality indicators of the finished product. Results of organoleptic and physicochemical indicators, the most optimal level of spirulina administration was established, which was 2%. Analysis of the results of changes in the peroxide value in the pate samples during storage showed the presence of a high antioxidant activity of spirulina, which will extend the shelf life of the finished product.
We present new results on catagenetic alteration of dispersed organic matter (DOM) and individual hydrocarbon composition of bitumen extracts from the lower mesocatagenesis and apocatagenesis zone, based on the study of core samples from superdeep well SV-27 (Vilui syneclise), which penetrated Permian and Upper Carboniferous coal-bearing strata. The vitrinite reflectance data show a progressive increase in the thermal maturity of DOM at a depth of ~4 km. The major biomarker indicators of the thermal history of DOM in the central part of the Vilyui syneclise appear to play only a minor role below this depth, thus reflecting the early stages of mesocatagenesis. The pristane/phytane ratios begin to invert at the same depth. Bitumen extracts from core samples collected from this depth contain new hydrocarbons in trace amounts, which increase with depth. The identified compounds include homologous series of alkenes, 2,4- and 2,7-dimethylalkanes, and alkylcyclohexanes with a prevalence of compounds with an odd carbon number predominance. Unusual differentiation of aliphatic and cyclic hydrocarbons with even and odd carbon-numbered chains occurs at the maximum depth (6458 m). Among aromatic hydrocarbons, four new diastereomers are identified: 17-desmethyl–23-methylmonoaromatic steroids C27. Considerable variations in the composition of bitumen extracts from the apocatagenetically altered core samples appear to reflect the termination of hydrocarbon generation from kerogen and further thermolysis of residual bitumens, including their asphaltene components. This explains the low values of maturity biomarker indicators corresponding to the apocatagenesis grade, since in this case they reflect the composition of hydrocarbons generated during the early stages and later occluded and adsorbed by asphaltenes. “Deep-seated” microoil from Permian, Carboniferous, and Cambrian deposits did not participate in the formation of oil rims and major gas condensate pools in the Vilyui petroleum area.
—The homologous series of high-molecular weight dimethylalkanes (HMWDMAs) with either odd- or even-numbered carbon chains in the range from C19–20 to C30–31 have been identified in organic matter from recent and partially lithified deposits of Siberia and the Russian Platform by chromatography–mass spectrometry. The first homologous series is represented by even-numbered 3,4-HMWDMAs followed by the alternation of odd-numbered 3,5-HMWDMAs, even-numbered 3,6-HMWDMAs, and odd-numbered 3,7-HMWDMAs. The most abundant are 3,7-dimethylalkanes. The microbial origin of high-molecular weight dimethylalkanes is the most likely explanation for their presence in the fossil organic matter. The precursors of HMWDMAs might have been tetra- and diether lipids of archaea and bacteria. It is assumed that HMWDMAs and other immature hydrocarbons from great depths (SV-27 and SG-6 superdeep boreholes) result from the decomposition of asphaltenes, which occluded the related compounds inside their structure during the early stages of generation and carried them unchanged throughout the “oil window”.
—The organic-geochemistry data reveal two levels in the reference Upper Jurassic–Lower Cretaceous section of the lower reaches of the Olenek River: lower (Volgian–lower Boreal Berriasian (diasterene)) and upper (Boreal Berriasian–Valanginian (hopane)). The Volgian beds are composed of clays with abundant prasinophytes Leiosphaeridia and Tasmanites and various dinocyst assemblages and have the highest content of organic carbon (Corg), up to 9%. Isoprenoids, in particular, pristane and phytane, are highly predominant among aliphatic hydrocarbons; their content is more than three times higher than that of coeluting n-alkanes, which is typical of buried chlorophyll-containing plankton (dinocysts and prasinophytes). Sedimentological, biofacies, and paleoecological analyses show that the highly carbonaceous beds of the Buolkalakh Formation formed under oxygen deficit conditions. An integrated analysis demonstrated that the pristane/phytane ratio does not always reliably reflect the reducing or oxidizing conditions of organic-matter accumulation and diagenesis. The discrepancy between the geochemical identification of organic matter according to the pristane/phytane ratio and the biofacies and sedimentological data is due to the low catagenetic maturity of OM. The Volgian was marked by a significant transgression of the Anabar–Lena sea, which was gradually changed by a successive regression of its basin at the end of this stage and in the Boreal Berriasian. The Corg contents in the coastal and subcontinental sediments decreased. Diasterenes and 4-methyldiasterenes disappeared from the balance of biomarker molecules, and the portion of hopanoids increased. Aerobic environments prevailed in the subbottom waters. Earlier, three biomarker horizons were identified according to geochemical criteria in the synchronous sections of Anabar Bay (Laptev Sea coast): terpane, diasterene, and hopane ones. In the section of the Olenek basin, the upper two horizons are well identified by specific biomarkers, and the lower one is absent because of the sedimentation break. Stratigraphic analysis of the location of these geochemical levels in different parts (and bathymetric zones) of the Anabar–Lena basin shows their diachronous formation. According to all geological and geochemical criteria, the Volgian Stage and the lower beds of the Boreal Berriasian Stage of this basin have a high petroleum potential. In the axial zone of the basin and, especially, on the Laptev Sea shelf, there were probably favorable conditions for the generation and accumulation of hydrocarbons genetically related to the Upper Jurassic highly carbonaceous rocks.
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