In this work, photocatalytic degradation of organic dyes such as methylene blue (MB) and indigo carmine (IC) have been studied by composite nanofibers systems containing cellulose acetate (CA), multiwall carbon nanotubes (CNT) and TiO 2 nanoparticles under UV light. The amino factionalized TiO 2 -NH 2 NPs cross-linked to the CA/CNT composite nanofibers works as a semiconductor catalyst. The morphology and crystallinity were characterized by scanning electron microscopy, transmission electron microscopy (TEM), X-ray diffraction, and Fourier transform infrared spectroscopy. It was also seen that many factors affected the photodegradation rate, mainly the pH of the solution and the dye concentration, temperature, etc. The study demonstrated that IC degrades at a higher rate than MB. The maximum photodegradation rate of both organic dyes was achieved at a pH 2. In comparison to other studies, this work achieved high photodegradation rate in lower time and using less power intensity.
Cellulose acetate/carbon nanotube composite nanofibers were prepared using electrospinning technique. The morphology, crystalline, and mechanical properties were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), and tensile test. The result indicated that the CA with 0.5 wt% CNT shows better mechanical properties among the other sample which contains lower or higher percent of CNT. In addition, the diameter of the average fibers was 415 ± 45 nm and shows good dispersions of CNT into the nanofibers. Moreover, tensile strength and Young's modulus were enhanced with an average of 67% and 78%, respectively.
K E Y W O R D Scarbon nanotubes, cellulose acetate, composite nanofibers, electrospinning, mechanical properties
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