This study aimed at investigating the influence of microstructure on mechanical properties of Harmonic Structured (HS) pure-Ni compacts. The harmonic structure is a heterogeneous microstructure with a spatial distribution of fine grains (FG) and coarse grains (CG), that is, the CG areas ('Core') embedded in the matrix of three-dimensionally continuously connected network of FG areas ('Shell'). The HS pure-Ni samples were fabricated by powder metallurgy route consisting of mechanical milling (MM) of plasma rotated electrode processed pure-Ni powder and subsequent sintering by Spark Plasma Sintering. The plastic deformation at powder particle surface increases with increasing MM time. As a result, after sintering, shell fraction also increases in the HS pure-Ni samples. It was found that the fraction of a "shell" area is an important parameter controlling the balance of the mechanical properties of the HS pure-Ni compacts. The HS pure-Ni with a higher fraction of "shell" area demonstrated higher strength and approximately similar elongation as compared to the homo Ni samples and HS pure-Ni samples containing low shell fraction. Moreover, the effects of strain hardening rates and strain hardening exponents on deformation behaviour of HS pure-Ni samples were also discussed.
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