The wetting of solid surfaces can be modified by altering the surface free energy balance between the solid, liquid and vapour phases. Here we show that liquid dielectrophoresis (L-DEP) induced by non-uniform electric fields can be used to enhance and control the wetting of dielectric liquids. In the limit of thick droplets, we show theoretically that the cosine of the contact angle follows a simple voltage squared relationship analogous to that found for electrowetting-on-dielectric (EWOD). Experimental observations confirm this predicted dielectrowetting behavior and show that the induced wetting is reversible. Our findings provide a non-contact electrical actuation process for meniscus and droplet control.

The ability to quickly spread a liquid across a surface and form a film is fundamental for a diverse range of technological processes, including printing, painting and spraying. Here we show that liquid dielectrophoresis or electrowetting can produce wetting on normally nonwetting surfaces, without needing modification of the surface topography or chemistry. Additionally, superspreading can be achieved without needing surfactants in the liquid. Here we use a modified Hoffman-de Gennes law to predict three distinct spreading regimes: exponential approach to an equilibrium shape, spreading to complete wetting obeying a Tanner's law-type relationship and superspreading towards a complete wetting film. We demonstrate quantitative experimental agreement with these predictions using dielectrophoresis-induced spreading of stripes of 1,2 propylene glycol. Our findings show how the rate of spreading of a partial wetting system can be controlled using uniform and non-uniform electric fields and how to induce more rapid superspreading using voltage control.

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Electrowetting charges the solid-liquid interface to change the contact area of a droplet of a conducting liquid. It is a powerful technique used to create variable focus liquid lenses, electronic paper and other devices, but it depends upon ions within the liquid. Liquid dielectrophoresis (L-DEP) is a bulk force acting on the dipoles throughout a dielectric liquid and is not normally considered to be a localized effect acting at the interface between the liquid and a solid or other fluid. In this work, we show theoretically how non-uniform electric fields generated by interdigitated electrodes can effectively convert L-DEP into an interface localized form. We show that for droplets of sufficient thickness, the change in the cosine of the contact angle is proportional to the square of the applied voltage and so obeys a similar equation to that for electrowetting -this we call dielectrowetting. However, a major difference to electrowetting is that the strength of the effect is controlled by the electrode spacing and the liquid permittivity rather than the properties of an insulator in a sandwich structure. Experimentally, we show that that this dielectrowetting equation accurately describes the contact angle of a droplet of oil viewed across parallel interdigitated electrodes. Importantly, the induced spreading can be complete, such that contact angle saturation does not occur. We then show that for thin films, L-DEP can shape the liquid-air interface creating a spatially periodic wrinkle and that such a wrinkle can be used to create a voltage programmable phase diffraction grating.

Walkers are dual objects comprising a bouncing droplet dynamically coupled to an underlying Faraday wave at the surface of a vibrated bath. In this paper, we study the wave-mediated interaction of two walkers launched at one another, both experimentally and theoretically. Different outcomes are observed in which either the walkers scatter or they bind to each other in orbits or promenade-like motions. The outcome is highly sensitive to initial conditions, which is a signature of chaos, though the time during which perturbations are amplified is finite. The vertical bouncing dynamics, periodic for a single walker, is also strongly perturbed during the interaction, owing to the superposition of the wave contributions of each droplet. Thanks to a model based on inelastic balls coupled to the Faraday waves, we show that this perturbed vertical dynamics is the source of horizontal chaos in such a system.