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Summary: Hydrosilylation reaction of 2.4.6.8-tetrahydro-2.4.6.8-tetramethylcyclotetrasiloxane with allyl glycidyl ether at 1:4.1 molar ratios of initial compounds in the presence of platinum hydrochloric acid (0.1 M solution in THF), Karstedt's catalyst (Pt 2 [(VinSiMe 2 ) 2 O] 3 ) and platinum on the carbon have been studied and 2.4.6.8-tetrapropyl glycidyl-2.4.6.8-tetramethylcyclotetrasiloxane has been obtained. For hydrosilylation reaction order, rate constants and activation energy have been determined in the presence of Karstedt's catalyst. Ring-opening polymerization reaction of D 4 R in the presence of catalytic amount of powder-like potassium hydroxide has been carried out. Linear methylsiloxane oligomer with regular arrangement of propyl glycidyl groups in the side chain has been obtained. The reaction of epoxy group containing compounds with primary and secondary amines has been carried out and corresponding amino hydroxyl groups containing compounds have been obtained. The synthesized organosiloxanes were studied by FTIR, 1 H, 13C and 29 Si NMR spectroscopies. Comb-type oligomers were characterized by sizeexclusion chromatography, wide-angle X-ray methods. Via sol-gel processes of 2.4.6.8-tetrapropyl glycidyl-2.4.6.8-tetramethylcycltetrasiloxane, ethylene diamine and tetraethoxysilane doped with lithium trifluoromethylsulfonate (triflate) or lithium bis(trifluoromethylsulfonyl)imide solid polymer electrolyte membranes have been obtained. The dependence of ionic conductivity as a function of temperature and salt concentration has been studied. It is shown that the conductivity of membrane containing 15 wt % of triflate type salt concentration is higher on the 3 orders than analogous containing the same amount of the salt lithium bis(trifluoromethylsulfonyl)imide. The difference is described in terms of ion mobilities in the polymer matrix.

We have obtained ceramic composites containing graphene structure, where homogenization process of powdery composite was improved. At first, α-alumina was obtained from local row, which is cheap and available. The obtaining method was developed by our group. Graphene oxide was synthesized from natural graphite. Homogenization was carried out in nanomill with organic binder, which provides for equal distribution and separation of graphene oxide layers (Organic binder behaves as “scotch tape”) during grinding. Some characteristics of ceramic materials have been improved.

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− Hydrosilylation reactions of 2.4.6.8-tetrahydro-2.4.6.8-tetramethylcyclotetrasiloxane with allyl butyrate catalyzed by Karstedt's, H 2 PtCl 6 and Pt/C catalyst were studied and 2.4.6.8-tetra (propyl butyrate)-2.4.6.8-tetramethylcyclotetrasiloxane was obtained. The reaction order, activation energies and rate constants were determined. Ringopening polymerization of 2.4.6.8-tetra (propyl butyrate)-2.4.6.8-tetramethylcyclotetrasiloxane in the presence of CaF 2 , LiF, KF and anhydrous potassium hydroxide in 60-70 o C temperature range was carried out and methylsiloxane oligomers with regular arrangement of propyl butyrate pendant groups were obtained. The synthesized products were studied by FTIR and NMR spectroscopy. The polysiloxanes were characterized by wide-angle X-ray, gel-permeation chromatography and DSC analyses. Via sol-gel processes of oligomers doped with lithium trifluoromethylsulfonate or lithium bis (trifluoromethylsulfonyl)imide, solid polymer electrolyte membranes were obtained. The dependences of ionic conductivity of obtained polyelectrolytes on temperature and salt concentration were investigated, and it was shown that electric conductivity of the polymer electrolyte membranes at room temperature changed in the range 3.5×10 -4~6.4×10-7 S/cm.