Lead-containing piezoelectric materials typically show the highest energy conversion efficiencies, but due to their toxicity they will be limited in future applications. In their bulk form, the piezoelectric properties of lead-free piezoelectric materials are significantly lower than lead-containing materials. However, the piezoelectric properties of lead-free piezoelectric materials at the nano scale can be significantly larger than the bulk scale. This review looks at the suitability of ZnO nanostructures as candidate lead-free piezoelectric materials for use in piezoelectric nanogenerators (PENGs) based on their piezoelectric properties. Of the papers reviewed, Neodymium-doped ZnO nanorods (NRs) have a comparable piezoelectric strain constant to bulk lead-based piezoelectric materials and hence are good candidates for PENGs. Piezoelectric energy harvesters typically have low power outputs and an improvement in their power density is needed. This review systematically reviews the different composite structures of ZnO PENGs to determine the effect of composite structure on power output. State-of-the-art techniques to increase the power output of PENGs are presented. Of the PENGs reviewed, the highest power output belonged to a vertically aligned ZnO nanowire (NWs) PENG (1-3 nanowire composite) with a power output of 45.87 μW/cm2 under finger tapping. Future directions of research and challenges are discussed.

The viability for dry coupling of piezoelectric ultrasonic transducer components was investigated, using a thin foil of annealed silver as a filler material/coupling agent at each component interface. Criteria used for room temperature evaluation were centered on signal-to-noise ratio (SNR) and echo bandwidth, for a Li-Nb based transducer operating in pulse-echo mode. A normal clamping stress of only 25 MPa, applied repeatedly over three loading cycles on a precisely-aligned transducer stack, was sufficient to yield backwall echoes with a SNR greater than 25 dB, and a 3 dB bandwidth of approximately 65%. This compares to a SNR of 32 dB and a 3 dB bandwidth of 65%, achievable when all transducer interfaces were coupled with ultrasonic gel. The respective roles of a soft filler material, alignment of transducer components, cyclic clamping, component roughness, and component flatness were evaluated in achieving this high efficiency dry coupling, with transducer clamping forces far lower than previously reported. Preliminary high temperature tests indicate that this coupling method is suitable for high temperature and achieves signal quality comparable to that at room temperature with ultrasonic gel.

Long-term installation of ultrasonic transducers in high temperature environments allows for continuous monitoring of critical components and processes without the need to halt industrial operations. Transducer designs based on the high-Curie-point piezoelectric material lithium niobate have been shown to both be effective and stable at extreme temperatures for long-term installation. In this study, several brazing techniques are evaluated, all of which aim to provide both mechanical bonding and acoustic coupling directly to a bare lithium niobate piezoelectric element. Two brazing materials—a novel silver-copper braze applied in a reactive air environment and an aluminum-based braze applied in a vacuum environment—are found to be suitable for ultrasound transmission at elevated temperatures. Reliable wide-bandwidth and low-noise ultrasound transmission is achieved between room temperature and 800 °C.