Surface temperature is a fundamental parameter of Earth's climate. Its evolution through time is commonly reconstructed using the oxygen isotope and the clumped isotope compositions of carbonate archives. However, reaction kinetics involved in the precipitation of carbonates can introduce inaccuracies in the derived temperatures. Here, we show that dual clumped isotope analyses, i.e., simultaneous Δ 47 and Δ 48 measurements on the single carbonate phase, can identify the origin and quantify the extent of these kinetic biases. Our results verify theoretical predictions and evidence that the isotopic disequilibrium commonly observed in speleothems and scleractinian coral skeletons is inherited from the dissolved inorganic carbon pool of their parent solutions. Further, we show that dual clumped isotope thermometry can achieve reliable palaeotemperature reconstructions, devoid of kinetic bias. Analysis of a belemnite rostrum implies that it precipitated near isotopic equilibrium and confirms the warmer-than-present temperatures during the Early Cretaceous at southern high latitudes.

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The Nördlinger Ries and the Steinheim Basin are widely perceived as a Middle Miocene impact crater doublet. We discovered two independent earthquake-produced seismite horizons in North Alpine Foreland Basin deposits. The older seismite horizon,associated with the Ries impact is overlain by in situ-preserved distal impact ejecta, forming a unique continental seismite-ejecta couplet within a distance up to 180 km from the crater. The younger seismite unit, also triggered by a major palaeo-earthquake, comprises clastic dikes that cut through the Ries seismite-ejecta couplet. The clastic dikes were likely formed in response to the Steinheim impact, some kyr after the Ries impact, in line with paleontologic results. With the Ries and Steinheim impacts as two separate events, Southern Germany witnessed a double disaster in the Middle Miocene. The magnitude-distance relationship of seismite formation during large earthquakes suggests the seismic and destructive potential of impact-earthquakes may be signi cantly underestimated.

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