Empty fruit bunches (EFB) is one of solid waste from crude palm oil (CPO) mill. It’s about 20-22% from fresh fruit bunches (FFB) or equal to the CPO yield. Indonesian CPO production in 2019 was 51.8 million tons; increased by 9% compared to 2018. So, about 51.8 million tons of EFB was available in 2019. EFB is a potential lignocellulosic material for pulp and paper. The utilization of EFB fibers for papermaking has been studied extensively. The use of EFB for printing and writing papers tends to cause pitch problems and poor visual appearance. The most potential use of EFB fibers is for packaging papers. EFB fiber is classified as short up to moderate fibers, so its usage must still be mixed with other fibers to improve the sheet strength. Many experiments have been done regarding the mixture of EFB fibers with other fibers such as OCC (Old Corrugated Containers) and UBC (Used Beverage Cartons) recycled fibers. Other types of paper from EFB are still being developed, including for nursery bags and active packaging papers.
The use of recycled fibers derived from old corrugated cardboard (OCC) potential for enhanced strength properties through the addition of carboxy methylcellulose (CMC). Research carried out on local OCC with variation of time reaction, temperture, and the dosage of of CMC and CaCl2. Handsheet laboratory was made, and then analyzed the strength properties include tensile index, tensile energy absorption (TEA) index , bursting index and folding endurance, as well as coarseness and kink. The results show the optimum condition is achieved on the conditions of the reaction time of 20 minutes, the reaction suhue 25°C, the concentration of CMC 0,75% and concentration CaCl2 0,5% . Strength properties improvement was achieved at 3,07% tensile index, folding endurance 43,75% and bursting strength 36,81% .Keywords: CMC, OCC, strength properties ABSTRAKSifat kekuatan serat daur ulang yang berasal dari kotak karton gelombang (KKG) bekas berpotensi untuk ditingkatkan melalui penambahan karboksi metil selulosa (CMC). Penelitian dilakukan terhadap KKG bekas lokal dengan variasi waktu, suhu, dan dosis penambahan CMC dan CaCl2. Lembaran kertas dibuat secara laboratorium , kemudian dianalisis sifat kekuatan meliputi indek tarik, indek tensile energy absorption (TEA), indek retak, dan ketahanan lipat, serta analisis coarseness dan kink. Hasil penelitian menunjukan kondisi optimum dicapai pada waktu reaksi 20 menit, suhu reaksi 25°C, konsentrasi CMC 0,75% dan konsentrasi CaCl2 0,5%. Peningkatan kekuatan yang dihasilkan adalah indeks tarik 3,07%, ketahanan lipat 43,75% dan indeks retak 36,81%.Kata kunci: CMC, KKG bekas, sifat kekuatan
Indonesia merupakan penghasil limbah plastik terbesar kedua setelah Cina, sehingga telah menjadi isu lingkungan. Salah satu kemasan plastik yang banyak digunakan adalah kemasan untuk pembibitan terbuat dari plastik atau dikenal sebagai polybag. Guna membantu mengurangi penggunaan polybag, telah dilakukan percobaan skala laboratorium pembuatan paper bag dari pulp tandan kosong sawit (TKS) sebagai pengganti polybag. Penelitian ini bertujuan untuk mendapatkan formula pembuatan paper bag yang dapat memenuhi persyaratan penggunaan akhirnya. Kegiatan dimulai dari penggilingan pulp TKS, dilanjutkan dengan pembuatan lembaran dengan variasi gramatur 90 g/m2 dan 125 g/m2 pada rentang pH 7-8. Dua jenis bahan kimia penguat basah yang digunakan yakni polietilen imin (PEI) dan poliamin epiklorohidrin (PAE), ditambahkan dengan variasi dosis 1,0 – 2,0 % terhadap berat kering serat. Karakteristik lembaran dievaluasi melalui uji ketahanan tarik, daya regang, daya serap energi (tensile energy absorption atau TEA), ketahanan retak, ketahanan sobek, persen rendemen kekuatan setelah mengalami pembasahan, dan porositas. Uji biodegradabilitas dilakukan untuk melihat tingkat afiliasi bahan kimia yang ditambahkan terhadap lingkungan dan rasio C/N (rasio karbon/nitrogen) untuk mengetahui kontribusinya terhadap proses pengomposan. Hasil percobaan menunjukkan bahwa lembaran memiliki rendemen ketahanan tarik di atas 10%. Gramatur berkorelasi positif terhadap sifat kekuatan, dan negatif terhadap porositas. PAE memberikan sifat kekuatan lebih tinggi dibanding PEI, namun PEI memberikan persen rendemen ketahanan tarik lebih tinggi dibanding PAE. Seluruh bahan kimia yang ditambahkan dapat didegradasi lebih dari 60% dalam kurun waktu 28 hari namun uji rasio C/N menunjukkan hasil yang belum memadai. Formula optimum diperoleh pada gramatur 125 g/m2 dengan penambahan PEI 2%. Paper Bag Based on Empty Fruit Bunches Pulp as an Alternative for Polybag Substitute in Pre-Nursery Palm Oil PlantationAbstract Indonesia is the second-largest plastic waste producer after China, so it has become an environmental issue. One of the plastic packagings which are large in consumption for nursery packaging is known as polybag. Therefore, to reduce the use of plastic bag, the laboratory scale experiment of paper bag made from oil palm empty fruit bunches (EFB) as polybag substitutes has been done. This study aims to obtain a formula for paper bags that can meet the end using requirements. Laboratory scale started from beating the EFB pulp, then continued with handsheet making at grammage variation of 90 g/m2 and 125 g/m2 with a pH range of 7-8. Two types of wet strength agents were used, namely polyethyleneimine (PEI) and polyamine epichlorohydrin (PAE) which were varied from 1.0 to 2.0% (%db of fiber). Sheet properties were evaluated through tensile and bursting strength, stretch, TEA tests, tearing resistance, % yield of strength after wetting, opacity, and porosity. A biodegradability test was conducted to determine the chemical’s affiliation level to the soil and the C/N ratio to know its contribution to the composting process. The results showed that the paper bag has a tensile strength yield above 10%. Grammage is directly proportional to strength properties and inversely to porosity. PAE gave higher strength than PEI but is lower in % yield of tensile strength. All added chemicals can be degraded by more than 60% within 28 days but the C/N ratio test showed inadequate results. The optimum formula was obtained at 125 g/m2 and PEI of 2.0%.
This research has been conducted through several steps.Step I was base papermaking using 80% LBKP and 20 % NBKP. They were refine separately up to 300 ml CSF, then mixed with 15% CaCO3, 0.6% AKD, 0.5% poliacrylamide, and 1,5% cationic starch to dry-weight of fibers.Step II was modifying starch enzymaticaly at 70-75°C, pH 6.5 -7.0 ABSTRAKPenelitian ini dilakukan melalui beberapa tahapan. Tahap I adalah pembuatan kertas dasar dengan menggunakan bahan baku 80% serat pendek atau leaf bleached kraft pulp (LBKP) dan 20% serat panjang atau needle bleached kraft pulp ( NBKP) digiling secara terpisah hingga mencapai derajat giling 300 ml CSF. Selanjutnya pulp dicampur ke dalam bahan kimia yang terdiri 15 % CaCO 3 , 0,6% AKD, 1,5% pati kationik dan Poliakrilamida sebesar 0,5% terhadap berat kering pulp. Lembaran dibuat pada gramatur 60 g/m 2 . Tahap II adalah pembuatan pati termodifikasi enzimatis pada kondisi inkubasi suhu sekitar 70 -75 0 C, pH : 6,5 -7,0, waktu selama 15 menit dengan penambahan amilase sebesar 0,05%. Tahap III adalah proses penyalutan kertas dasar dengan pati termodifikasi enzimatis, sebagai pembanding menggunakan pati alam maupun pati komersial. Kemudian dilakukan pengujian terhadap lembaran yang dihasilkan meliputi : derajat putih, kekasaran, penetrasi minyak, ketahanan cabut, daya serap air dan pH. Selanjutnya dilakukan uji coba di industri dengan komposisi pigmen kaolin dan kalsium karbonat 40 : 60 menggunakan pati enzim, pati komersial, dan pati alam. Hasil percobaan menunjukkan bahwa viskositas untuk pati alam, pati enzim dan pati komersial masing-masing adalah sebasar 8000 cPs, 26 cPs dan 114 cPs. Penggunaan pati modifikasi enzim memberikan sifat kertas yang paling baik. Hasil replikasi percobaan di laboratorium industri, pati enzim juga menghasilkan sifat kertas yang lebih baik.Kata kunci: pati, kertas cetak salut, amilase, viskositas.
The strength properties of paper are strongly affected by fiber quality. The objective of this study was to assess the effect of modification fiber by carboxymethylation of leaf bleached kraft pulp (LBKP) and deinked pulp (DIP) by using carboxymethyl cellulose (CMC). Carboxymethylation was carried out by addition of various concentration of CMC and cationic agent of CaCl2. Handsheets with 70 gsm were made from the stock, and the physical properties were tested as the tensile index, stretch, tensile energy absorption (TEA), tearing index, and bursting index as well as SEM analysis. The results showed that the highest increase of fiber strength of LBKP and DIP was achieved by addition of 1% CMC and 9.19% CaCl2. For LBKP, the increasing of tensile index was 18.1%, stretch 27%, TEA 30.2%, tear index 7,8 % and burst index 16,7%. Whereas for DIP, the increasing of tensile index reached 29.9%, stretch 22.2%, TEA 61.2%, tear index 20.7% and burst index 63.1%. From the results of SEM analysis showed that the addition of CMC and CaCl2 increased fiber bonding.Keywords: CMC, LBKP, DIP ABSTRAK Sifat kekuatan kertas sangat dipengaruhi oleh kualitas serat. Tujuan penelitian ini adalah untuk mengetahui pengaruh modifikasi serat kraft putih kayu daun (LBKP) dan serat hasil deinking (DIP) dengan karboksimetilasi menggunakan karboksimetil selulosa (CMC). Modifikasi secara karboksimetilasi dilakukan dengan variasi penambahan CMC dan sebagai cationic agent CaCl2. Lembaran dibuat dari stok dengan gramatur 70 gsm, kemudian dilakukan pengujian fisik dengan parameter indeks tarik, regang, TEA, indeks sobek dan indeks retak. Selain itu lembaran juga diuji morfologi dan SEM. Hasil penelitian menunjukan peningkatan kekuatan lembaran tertinggi dicapai oleh LBKP maupun DIP, pada kondisi penambahan 1% CMC and 9.19% CaCl2. Untuk LBKP peningkatan indeks tarik adalah 18,1%, regang 27%, TEA 30,2%, indeks sobek 7,8 % dan indeks retak 16,7%. Sedangkan untuk DIP, peningkatan indeks tarik mencapai 29,9%, regang 22,2%, TEA 61,2%, indeks sobek 20,7% dan indeks retak 63,1%. Hasil analisa SEM menunjukan bahwa dengan penambahan CMC dan CaCl2, mengakibatkan terjadi peningkatan ikatan antar serat.Kata kunci: CMC, LBKP, DIP
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