The possibility of obtaining effective wall materials and technological lightweight products for high-temperature insulation by introducing the expanded vermiculite into the ceramic mass is investigated. Mineralogy of used clays and vermiculites was studied. They are represented by minerals of the same class, and therefore weak adhesion of smooth surfaces of vermiculite grains is compensated by common genetic origin with the matrix of the basic material of the composite. Thermotechnical studies of the process of swelling of vermiculite in a quartz furnace showed that to obtain a relatively high mechanical strength of vermiculite grains, it is necessary to select the maximum temperature and the mode of swelling, so that the planar shape of vermiculite plates remains and there is no pronounced warping. The degree of thermal delamination is influenced by the particle size, the increase of which entails a deterioration in physical and mechanical properties. The introduction of a high percentage of vermiculite additives in the charge allows to obtain lightweight thermal insulation products.
Abstract. We presented a study on the possibility of using the burnt rocks of the Krasnoyarsk Territory for production of chemically-bonded materials in the form of bricks which are so widely used in multistory housing and private house construction. The radiographic analysis of the composition of burnt rock was conducted and a modifier to adjust the composition uniformity was identified. The mixing moisture content was identified and optimal amount at 13-15% was determined. The method of semidry pressing has been chosen. The process of obtaining moldings has been theoretically proved; the advantages of chemically-bonded wall materials compared to ceramic brick were shown. The production of efficient artificial stone based on material burnt rocks, which is comparable with conventionally effective ceramic materials or effective with cell tile was proved, the density of the burned clay-based cell tile makes up to 1630-1785 kg \ m 3 , with compressive strength of 13.6-20.0 MPa depending on the compression ratio and cement consumption, frost resistance index is F50, and the thermal conductivity in the masonry is λ = 0,459-0,546 W \ m * 0 C. The clear geometric dimensions of pressed products allow the use of the chemically-bonded brick based on burnt clay as a facing brick.
The article describes the loam of the Kubekovsky deposit of the Krasnoyarsk Territory, which is widely used in the production of ceramic bricks in factories that produce wall materials. In the studies described in the article, mechanoactivation and modification were used to improve its technological and physico-mechanical characteristics. Mechanoactivation was carried out in a hydrodynamic dispersant. As the additive-modifier used waste stoneplant serpentinites of the Perevalnoye deposit. The effect of the additive-modifier on the properties of ceramic compositions is shown. It is shown that a small amount of serpentinite up to three percent -significantly increases the compressive strength of fired ceramic samples.If the composition has an additive of more than three percent, a decrease in strength characteristics is observed, this is related, probably due to the fact that most of the magnesium oxide remains unreacted. White inclusions areobserved visually in the structure of calcined samples throughout the volume. The combined effect of mechanoactivation and modification is shown, which makes it possible to improve the technological and physicomechanical characteristics of the ceramic shard. The results of electron microscopy are presented, suggesting that the microstructure of a ceramic shard activated with the addition of serpentinite contains moremullite-rich mixed crystals, as well as devitrified areas. Inclusions of magnesium oxide are not observed. Magnesium oxide in the ceramiccomposition serves as a primer capable of making the melt more liquid,accelerating its devitrification.
This article presents the results of experimental studies aimed at improving the physicomechanical properties of effective hollow ceramic stones using various technological methods that will disperse, homogenize and structure the ceramic mixture by introducing industrial waste with high alumina content, dispersed reinforcement, and also mechanical activation of the molding material, accompanied by the fragmentation of clay particles to a colloidal degree of dispersion, allows eliminating the aging process. The main molding characteristics of the investigated mixtures were determined, X-ray phase analysis of ceramic masses and a shard of the control composition was performed and after dispersion, activation modes were worked out, strength characteristics of ceramic samples made of dispersed clay raw materials were determined.
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