The world is currently going through the COVID-19 pandemic which has caused hundreds of thousands of deaths in just a few months. Considering the need for lockdown measures, most countries, including Malaysia, have implemented 'Movement Control Orders' (MCOs) as a prevention step to reduce the deadly spread of this disease. Local and worldwide media have reported the immediate improvement of air quality due to this event. Nevertheless, data on the effects of MCOs on air quality at local scales are still sparse. Here, we investigate changes in air quality during the MCO at an urban area using the air sensor network AiRBOXSense which measures monoxide (CO) and particulate matter (PM 2.5 and PM 10). In this study, air pollutant data during normal days were compared with MCO days using a reference analyser and AiRBOXSense. The results showed that the levels of the measured pollutants dropped by ~20 to 60% during the MCO days at most locations. However, CO in Kota Damansara (KD) dropped to 48.7%, but PM 2.5 and PM 10 increased up to 60% and 9.7% respectively during MCO days. Local burning activities in the residential area of KD are believed to be the main cause of the increased PM levels. This study has proven that air pollutant levels have significantly fallen due to the MCO. This air quality level information showed that the reduction of air pollutants can be achieved if traffic and industry emissions are strictly controlled.

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Abstract. Atmospheric measurements of the ozone-depleting substance CFC-113a (CCl3CF3) are reported from ground-based stations in Australia, Taiwan, Malaysia and the United Kingdom, together with aircraft-based data for the upper troposphere and lower stratosphere. Building on previous work, we find that, since the gas first appeared in the atmosphere in the 1960s, global CFC-113a mixing ratios have been increasing monotonically to the present day. Mixing ratios of CFC-113a have increased by 40 % from 0.50 to 0.70 ppt in the Southern Hemisphere between the end of the previously published record in December 2012 and February 2017. We derive updated global emissions of 1.7 Gg yr−1 on average between 2012 and 2016 using a two-dimensional model. We compare the long-term trends and emissions of CFC-113a to those of its structural isomer, CFC-113 (CClF2CCl2F), which still has much higher mixing ratios than CFC-113a, despite its mixing ratios and emissions decreasing since the 1990s. The continued presence of northern hemispheric emissions of CFC-113a is confirmed by our measurements of a persistent interhemispheric gradient in its mixing ratios, with higher mixing ratios in the Northern Hemisphere. The sources of CFC-113a are still unclear, but we present evidence that indicates large emissions in East Asia, most likely due to its use as a chemical involved in the production of hydrofluorocarbons. Our aircraft data confirm the interhemispheric gradient as well as showing mixing ratios consistent with ground-based observations and the relatively long atmospheric lifetime of CFC-113a. CFC-113a is the only known CFC for which abundances are still increasing substantially in the atmosphere.

Chlorofluorocarbons (CFCs) are ozone-depleting substances as well as strong greenhouse gases, and the control of their production and use under the Montreal Protocol has had demonstrable benefits to both mitigation of increasing surface UV radiation and climate forcing. A global ban on consumption came into force in 2010, but there is evidence of continuing emissions of certain CFCs from a range of sources. One compound has received little attention in the literature, namely CFC-114 (C2Cl2F4). Of particular interest here is the differentiation between CFC-114 (CClF2CClF2) and its asymmetric isomeric form CFC-114a (CF3CCl2F) as atmospheric long-term measurements in the peer-reviewed literature to date have been assumed to represent the sum of both isomers with a time-invariant isomeric speciation. Here we report the first long-term measurements of the two isomeric forms separately, and find that they have different origins and trends in the atmosphere. Air samples collected at Cape Grim (41 degrees S), Australia, during atmospheric background conditions since 1978, combined with samples collected from deep polar snow (firn) enable us to obtain a near-complete record of both gases since their initial production and release in the 1940s. Both isomers were present in the unpolluted atmosphere in comparably small amounts before 1960. The mixing ratio of CFC-114 doubled from 7.9 to 14.8 parts per trillion (ppt) between the start of the Cape Grim record in 1978 and the end of our record in 2014, while over the same time CFC-114a trebled from 0.35 to 1.03 ppt. Mixing ratios of both isomers are slowly decreasing by the end of this period. This is consistent with measurements of recent aircraft-based samples showing no significant interhemispheric mixing ratio gradient. We also find that the fraction of CFC-114a mixing ratio relative to that of CFC-114 increased from 4.2 to 6.9% over the 37-year period. This contradicts the current tacit assumption used in international climate change and ozone depletion assessments that both isomers have been largely co-emitted and that their atmospheric concentration ratio has remained approximately constant in time. Complementary observations of air collected in Taiwan indicate a persisting source of CFC-114a in South East Asia which may have been contributing to the changing balance between the two isomers. In addition we present top-down global annual emission estimates of CFC-114 and CFC-114a derived from these measurements using a two-dimensional atmospheric chemistry-transport model. In general, the emissions for both compounds grew steadily during the 1980s, followed by a substantial reduction from the late 1980s onwards, which is consistent with the reduction of emission in response to the Montreal Protocol, and broadly consistent with bottom-up estimates derived by industry. However, we find that small but significant emissions of both isomers remain in 2014. Moreover the inferred changes to the ratio of emissions of the two isomers since the 1990s also indicate that the sources...

Palm oil production is a key industry in tropical regions, driven by the demand for affordable vegetable oil. Palm oil production has been increasing by 9% every year, mostly due to expanding biofuel markets. However, the oil palm industry has been associated with key environmental issues, such as deforestation, peatland exploitation and biomass burning that release carbon dioxide (CO2) into the atmosphere, leading to climate change. This review therefore aims to discuss the characteristics of oil palm plantations and their impacts, especially CO2 emissions in the Southeast Asian region. The tropical climate and soil in Southeast Asian countries, such as Malaysia and Indonesia, are very suitable for growing oil palm trees. However, due to the scarcity of available plantation areas deforestation occurs, especially in peat swamp areas. Total carbon losses from both biomass and peat due to the conversion of tropical virgin peat swamp forest into oil palm plantations are estimated to be around 427.2 ± 90.7 t C ha−1 and 17.1 ± 3.6 t C ha−1 year−1, respectively. Even though measured CO2 fluxes have shown that overall, oil palm plantation CO2 emissions are about one to two times higher than other major crops, the ability of oil palms to absorb CO2 (a net of 64 tons of CO2 per hectare each year) and produce around 18 tons of oxygen per hectare per year is one of the main advantages of this crop. Since the oil palm industry plays a crucial role in the socio-economic development of Southeast Asian countries, sustainable and environmentally friendly practices would provide economic benefits while minimizing environmental impacts. A comprehensive review of all existing oil plantation procedures is needed to ensure that this high yielding crop has highly competitive environmental benefits.