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The pH effect of the precursor solutions on the phase, morphologies, and photocatalytic activity of Bi2MoO6synthesized by a hydrothermal reaction at 180°C for 20 h was investigated. X-ray powder diffraction (XRD), Raman spectroscopy, Fourier transform infrared (FTIR) spectrometry, scanning electron microscopy (SEM), and transmission electron microscopy (TEM) revealed the presence of pure orthorhombic well-crystallizedγ-Bi2MoO6nanoplates, including the symmetric (A1g) and asymmetric (A2u) stretching vibrations of the MoO6octahedrons involving the motion of apical oxygen atoms. The photocatalytic activity of Bi2MoO6nanoplates at the pH 6 determined via the decomposition of rhodamine-B (RhB) organic dye was the highest at 98.66% decolorization under Xe light irradiation.

In this research, the effects on reaction temperature and length of time on Bi2WO6nanoplates by hydrothermal synthesis on morphologies and photocatalytic properties were studied. The products obtained at different reaction temperature and reaction time were characterized by XRD, Raman, FTIR, SEM, and TEM techniques. The photocatalytic properties of the samples were measured by decomposing the rhodamine-B organic dye. XRD pattern was specified as pure orthorhombic well-crystallized Bi2WO6phase for the 180°C and 20 h synthesis. Its FTIR spectrum shows main absorption bands at 400–1000 cm−1, assigned to Bi–O stretching, W–O stretching, and W–O–W bridging stretching modes. SEM and TEM analyses show that the product was composed of nanoplates. Photocatalytic activity of Bi2WO6nanoplates shows the 98.24% degradation of rhodamine-B under the Xe light irradiation within 100 min.

One-dimensional cerium phosphate (CePO4) nanowires (NWs) were successfully synthesized by a facile and simple hydrothermal method at 200°C for 12 h, using Ce(NO3)3·6H2O and Na3PO4·12H2O as starting materials, and followed by pH adjusting to be 1–3 using HNO3 (conc.). Phase, morphologies, and vibration modes of the as-synthesized CePO4 products, characterized by XRD, SEM, TEM, and FTIR, were proved to be perfect and uniform monoclinic CePO4 nanowires with aspect ratio of more than 250 for the product synthesized in the solution with the pH of 1. The UV-visible and photoluminescence (PL) spectrometers were used to investigate optical properties of the as-synthesized monoclinic CePO4 nanowires.