The concentrations of As, Be, Cd, Cr, Hg, Mn, Ni, Pb, Sn, Tl, and V were determined in hair of 96 school children and in blood of 144 adults living in the vicinity of a hazardous waste incinerator (HWI) (Constantí, Tarragona County, Catalonia, NE Spain). The results were compared with those obtained in previous (1998 and 2002) surveys performed in the same area. Data were analyzed in terms of age, sex, and specific place of residence. Current mean concentrations in hair ranged between not detected (ND) (As, Be, and Tl) and 1.31 μg/g for Cr. In blood, Be, Hg, Mn, Sn, and Tl levels were under the respective detection limits. The mean blood concentrations of the remaining elements ranged from 0.34 μg/dL for Cd, to 2.40 μg/dL for Pb. Significant differences in hair and blood in relation to gender were only noted for Pb in blood. In general terms, metal concentrations in hair and blood from subjects living in Tarragona County are lower than most levels reported for other countries in recent years.
The purpose of this study was to assess the environmental impact of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) in the vicinity of a new hazardous waste incinerator (HWI) 4 years after regular operation of the facility. A double approach was carried out. The PCDD/F congener profiles corresponding to environmental samples, soil and herbage, collected before the HWI (baseline) and 4 years after starting regular operations, as well as PCDD/F profiles of air emission samples, were compared. The potential health risks (carcinogenic and noncarcinogenic) due to PCDD/F exposure were assessed for adults and children living in the neighborhood of the facility. Human exposure to PCDD/Fs was mainly due to dietary food intake. Comparisons between the PCDD/F congener profiles corresponding to the baseline and current surveys, as well as data concerning the human health risk assessment, indicate that the HWI in question does not cause additional risks to the environment orto the population living in the vicinity of the facility.
The concentrations of arsenic (As), cadmium (Cd), chromium (Cr), copper (Cu), mercury (Hg), manganese (Mn), nickel (Ni), and lead (Pb) were determined in samples of various edible vegetables (artichoke, cauliflower, lettuce, tomato), fruits (apple, mandarin, orange, pear) and rice grown in soils irrigated with water from the Ebro River in Tarragona Province (Catalonia, Spain). Although all food items were randomly acquired in various localities of the area, the local origin was always verified. Arsenic was only detected in rice (all samples) and apple (one sample), while Cd and Hg could not be detected in any of the samples. In general terms, metal concentrations were quite similar or lower than the levels recently reported in the literature. The health risks caused by metal exposure from consuming these agricultural products were assessed for the Catalan population living in the zone under evaluation. For all elements, when the lower bound values were considered, the Hazard Quotient (HQ) was <1, while using the Upper bound values, only for As (children and male seniors) HQ was >1. The intake of the analyzed elements through consumption of the nine selected food items does not mean additional health risks for the consumers of the area.
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