In acetonitrile solution HOF oxides CF3SSCF3 via With CH3CN at low temperatures HOF and HF form 1 : 1 ad-CF3S(0),SCF3 (n = 1, 2) to yield [CF3S(0)2]20. Analogously, ducts, whose structures have been elucidated by low-tem-CF,Se(O)OH and CF,SeX (X= C1, Br) are oxidized via perature X-ray structure analysis. Additional proof for the CF,Se(VI) intermediates to provide finally [CF,Se(O),],O. formation of CH3CN . HF in the liquid phase is provided.
Hypofluorous Acid and Acetonitrile: The Taming of a Reagent.-Treatment of a solution of water (10 wt.%) in acetonitrile (I) with fluorine (20 vol.% in argon) yields the 1:1 hydrogen-bonded complex ( II). Vibrational and NMR spectroscopic studies are described.-(APPELMAN, E. H.; DUNKELBERG, O.; KOL, M.; J.
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