The impact of climate on cultural heritage surfaces leads to several damage processes and the protection and the preservation of works of art is a challenge for conservation scientists and restorers. Traditional and innovative products are used in consolidating treatments in order to reduce the effects of the interaction environment-materials. The EC NANOMATCH Project aims at the development of innovative consolidating agents for carbonate matrices, wood and glass whose features should result in high compatibility, efficiency and long-lasting effect. In this project, metal alkoxides, molecular precursors for the deposition of metal carbonate are synthesized, characterized, tested and proposed as an alternative to traditional consolidating agents as well as to calcium hydroxide nanoparticles. This paper gives an overall description of the methodological approach adopted for the in field evaluation of durability taking into account the environmental impact. Preliminary results of the analyses carried out on carbonate stones aimed at investigating the features of the consolidating treatment are here presented and discussed.
Alkali-activated binders have shown great potential in the reuse of industrial waste materials and have therefore received significant attention. The use of one-part or a "just-add-water" alkali-activated binder aims to avoid the use of alkali-activator solutions which have traditionally been utilized in two-part systems. By using a solid activator, the disadvantages posed by hazardous liquid activators (such as the difficulties of using them on-site) can be minimized. Ceramic materials represent a considerable fraction of construction and demolition wastes, and originate not only from the building process, but also as tiles from industry and rejected bricks. Besides using these waste materials as road sub-base or construction backfill materials, they can also be employed as supplementary cementitious materials or even as raw material for alkali-activated binders. This paper presents the strength development and microstructural results obtained from examining different compositions under various curing conditions (sealing, ambient, and submerged in water). Two different ceramic wastes (with and without firing) were used as a partial replacement (5-10% by mass) of ground granulated blast-furnace slag. Specimens were then cured under three different curing regimes, including: (1) plastic-sealed, (2) unsealed at ambient conditions with an average temperature of 23 °C and 35% RH, and (3) submerged in water until the test date. Mechanical testing (compressive and flexural strengths) and microstructural analysis (SEM/EDX, XRD, MIP, heat of hydration, TGA, and DTA) were used to determine the effects of curing conditions. The results showed that ceramic waste content and type, as well as curing regimes, greatly affect the chemical reaction products, strength development, and structural stability. Keywords One-part alkali-activated binders • Ceramic wastes • Curing conditions • Mechanical properties Statement of Novelty This paper presents the effects of using three different curing conditions (sealed, ambient, and submerged in water) on strength development at early and final ages and the microscopic analysis of one-part alkali-activated slag/ceramic binders. Moreover, a comparative study is conducted on partial replacement of ground granulated blast-furnace slag by two different ceramic wastes as a binder type.
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