The concentration dissociation constants of nitrilotriacetic acid and the concentration stability constants of Cd(II) complexes with the nitrilotriacetic acid anion in water3ethanol mixtures and of Cu(II) and Cd(II) complexes with o-phenanthroline and 2,2`-bipyridine in micellar solutions of sodium dodecyl sulfate were determined potentiometrically. Based on the concentration constants determined, Cd 2+ and Cu 2+ buffer solutions were developed for calibration of a Cd 2+ -selective electrode in water3ethanol mixtures and Cd 2+ and Cu 2+ -selective electrodes in micellar solutions of sodium dodecyl sulfate within the ranges pCu 9.7313.5 and pCd 7.5311.8.
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