a Three-layer cross-oriented strand boards, OSB type 3 of 10 mm thick, were industrially manufactured from a mixture of wood species including 50% softwoods, 25% beech, and 25% low hardwoods, using a continuous press line. The effects of line speed and press factor on physical and mechanical properties of OSB/3 (exterior grade) were evaluated, keeping nearly constant the face-core adhesive ratio. The manufactured boards were classified into five groups depending on the pressing parameters. The experimental results showed that all mechanical properties increased, with increasing press factor and decreasing line speed. The ratios of bending strength (MOR) and the modulus of elasticity (MOE) parallel to perpendicular were 1.73 to 1.89 and 2.18 to 2.24, respectively. No significant differences in thickness swell and water absorption were observed. The lowest density was achieved at higher speed, although there was no large variation in densities between groups. Thickness swelling and internal bond after boil test exceeded the EN 300 standard requirements for OSB/3 moisture resistance, excepting a few boards. The results revealed that a correlation between speed and press factor is necessary in order to improve mechanical properties and to keep the physical performance of boards within a limited range of values.
The aim of this research was to evaluate the potential of magnesium lignosulfonate as adhesive in particleboard manufacturing. Diphenylmethane diisocyanate (PMDI) between 1% and 3% and glucose (1% of the lignosulfonate content) were added as potential cross-linkers in the adhesive formulations. Mixed beech and spruce wood, 30% beech wood and 70% spruce wood, were employed for the configuration of the panel structure. The density, mechanical properties and formaldehyde emission of single-layer particleboard were investigated. Spectroscopic analysis (FTIR) revealed structural changes brought by oxidation that may indicate depolymerization by the splitting of C-O-C bonds and formation of carbonyl groups. Mechanical properties were improved, and the highest average values were recorded for panels having as adhesives oxidized lignin with cross-linkers as follow: 15 N/mm2 (MOR), 3320 N/mm2 (MOE) and 0.48 N/mm2 (IB). The density profile presented higher values for faces in case of oxidized lignin panels. Changes were observed for oxidized lignin with cross-linker panels wherein the core had higher values. The results showed that the panels manufactured with adhesives composed of oxidized lignosulfonate (20% of the dried wood particles weight) and the addition of PMDI and glucose in various percentages have a positive influence on their formaldehyde release and mechanical properties requested by EN 312 (2004) standard.
Adhesives represent an important part in the wood-based composite production, and taking into account their impact on the environment and human health, it is a challenge to find suitable natural adhesives. Starting from the current concerns of finding bio-adhesives, this paper aims to use magnesium lignosulfonate in three adhesive recipes for particleboard manufacturing. First, the adhesive recipes were established, using oxygenated water to oxidize magnesium lignosulfonate (Recipe 1) and adding 3% polymeric diphenylmethane diisocyanate (pMDI) crosslinker (Recipe 2) and a mixture of 2% polymeric diphenylmethane diisocyanate with 15% glucose (Recipe 3). The particleboard manufacturing technology included operations for sorting particles and adhesive recipes, pressing the mats, and testing the mechanical strengths and formaldehyde emissions. The standardized testing methodology for formaldehyde emissions used in the research was the method of gas analysis. Tests to determine the resistance to static bending and internal cohesion for all types of boards and recipes were also conducted. The average values of static bending strengths of 0.1 N/mm2, 0.38 N/mm2, and 0.41 N/mm2 were obtained for the particleboard manufacturing with the three adhesive recipes and were compared with the minimal value of 0.35 N/mm2 required by the European standard in the field. Measuring the formaldehyde emissions, it was found that the three manufacturing recipes fell into emission classes E1 and E0. Recipes 2 and 3 were associated with good mechanical performances of particleboards, situated in the required limits of the European standards. As a main conclusion of the paper, it can be stated that the particleboards made with magnesium-lignosulphonate-based adhesive, with or without crosslinkers, can provide low formaldehyde emissions and also good mechanical strengths when crosslinkers such as pMDI and glucose are added. In this way magnesium lignosulfonate is really proving to be a good bio-adhesive.
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