Hexagonal arrangement of iron oxide nanoparticles was fabricated by utilizing a single-layered film of diblock copolymer micelles. The synthesis was directly performed on the solid substrate by oxygen plasma with preserving the dimensional order of micelles so that separate procedures for synthesis and deposition of nanoparticles were not necessary. Since the oxygen plasma treatment also eliminated polymers, pure patterns of iron oxide nanoparticles were obtained. Moreover, easy control over the size of nanoparticles enabled us to selectively create a ferrimagnetic or a superparamagnetic pattern of iron oxide nanoparticles without altering the fabrication process.
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A formalism is presented for determining the magnetoelastic (ME) coefficients of tetragonally distorted surfaces and thin films. The equation of motion of the magnetization is determined from free-energy-density expressions containing terms for crystalline and shape anisotropy, ME anisotropy, and applied field. Canonical magnetization curves, described by simple equations of motion and recorded under different strains, are shown to differ by an area equal to the magnetoelastic energy density. Thus, division of this area by the applied strain allows determination of the ME coefficients. A more general method is proposed which allows ME coefficients to be determined from arbitrarily shaped M-H curves taken at different strains by calculating the area between them over a conveniently chosen magnetization range. This reduces error in the ME coefficients by avoiding hysteretic effects at low fields and ambiguity about saturation at high fields. Examples are given that illustrate how the magnetic anisotropy and ME coefficients can be determined in three simple cases from Kerr or M-H loops in ultrathin films subjected to various bending strains.
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