In the present work, a novel study method of conductive liquids has been proposed. It is based on a discovered phenomenon of radiofrequency anisotropy of electrolyte solution, which arises in response to mechanical excitation of the solution. The phenomenon was observed during the development of a radiofrequency polarimetric contactless cardiograph. The electric field vector rotates after its transition through the pericardial region due to the acceleration changes of blood. Numerous in vitro experiments with monochromatic and impulse acoustic waves always induced the polarization rotation of the RF wave passing through an electrolyte solution. The response obtained from the solutions on acoustic excitation of the Heaviside function form demonstrates the effect of a solution “memory”. The dynamics of this process resembles the spin glasses magnetization. We hypothesized that there was a magnetic moment change within the solution, and the possible reason for it is an appearance of electromagnetic impulse caused by the same acoustic excitation. In a further experiment, we really captured a suspected electrical potential. Given that, we can declare at least three new physical effects never observed before for an electrolyte solution. The study method itself may provide broad options for remote measurement of the electrolyte solution parameters.
The correct references are listed below: 27. Kramarenko, A. V. Demo of non-contac polatimetric cardiograph testing, https:// www. youtu be. com/ watch?v= gOGvG jJ2QnI (Accessed 23 Jul 2020a). 43. Kramarenko, A. V. Demo of an industrial application (pump work control) of a non-contact rf registration device, https:// www. youtu be. com/ watch?v= z-1pzf3 iUyM (Accessed 3 Nov 2020b).
The present work is an effort to explain theoretically the physics of some processes we have observed in our previous experiments. They occur under any mechanical excitation in solutions of strong electrolytes. We assume that the occurrence of the low-frequency Debye ionic vibration potential (IVP) and the deviation of the RF polarization vector are conjugated, but only in the sense that the power flux density of some physical process "X" responsible for the rotation of the polarization vector is proportional to the square of the electric potential voltage. While the independence of the RF anisotropy appearance from the applied voltage and from the Debye potential in particular has been proved experimentally. An equivalent electrical circuit that simulates the observed effects within the solution excited by an acoustic wave is proposed and tested for physical feasibility. Special attention is paid to the basic theory of the ionic vibrational potential, namely, its predictions in the low-frequency range, which contradict both experiment and the energy conservation law. Given the futility of describing the "memory" effect as a process of electrical or molecular origin, several arguments are presented in favor of the fluid-gyroscopic mechanism. It was suggested that the rotation of the polarization vector of the RF signal is due to a change in the electric moment of the liquid atoms and/or the nuclear moment of ions having an odd mass number. The applications of the research are also supplemented. The results of new experiments show that the RF anisotropy of the solution is transported by the carrier. Accordingly, it is possible to create a completely contactless unitary sensor of velocity and inhomogeneities of the liquid, moreover, the experimental setup has previously confirmed the affordability of the idea.
In the present work, a novel conductive liquids method of study has been proposed. It is based on the phenomenon of radiofrequency anisotropy of electrolyte solution discovered by us. It arises in response to mechanical or acoustic excitation of the solution. We have observed the phenomenon during the development of an RF polarimetric contactless cardiograph. The electric field vector of the transmitted 433.82 MHz signal rotated after its transition through the pericardial region. That rotation depends on the change of blood acceleration when passing through the chambers of the heart and large vessels. It has also been revealed that rotation occurs after RF wave passage through the physiological saline (0.9% NaCl) subjected to any mechanical excitation inside it like a jet appearing or soundwave passing. No significant difference was detected experimentally between NaCl and KCl solutions behavior. It means that the mechanism of hydrodynamic separation of ions is apparently not suitable to explain the phenomenon. The response we have registered resembles the magnetization process of spin glasses. From the nature of the observed response, we have concluded that a fundamentally new physical effect is discovered. It may provide wide opportunities for remote measurement of the electrolyte solution parameters with polarized radio-frequency signals.
In this paper, we considered two phenomena in acoustically excited aqueous solutions of a strong electrolyte. These are the well-known Debye ionic vibrational potential (IVP), and radiofrequency anisotropy we discovered earlier , apparently, for the first time. Since both occur due to the accelerated motion of the solution, we have tried to combine them in one simple model. We have established that for a polarized UHF radio wave passed through a NaCl aqueous solution excited by an acoustic pulse the rotation angle of its vector E is proportional to the integral of the square of the observing IVP over time. An equivalent electrical circuit simulating the observed phenomena has been proposed and tested for physical feasibility. Several arguments are given in favour of the fluid-gyroscopic mechanism of RF anisotropy-related effects. We also found out that the IVP is practically independent of the vibrational velocity for frequencies below 10 kHz and it tends to zero at zero frequency. The latter is consistent with the law of conservation of energy but contradicts the incomplete existing theory.
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