The presented research is devoted to the study of geochemical transformation of environmental key objects (soils, surface and groundwater) within the solid waste landfills. The object of the study is the one of the largest landfills for solid waste disposal in Ukraine – Kyiv landfill №5. The main factual material, which is the basis of the article, was obtained by the authors during a comprehensive field ecological and geochemical research in 2018-2020. The aim of the work was to determine the geochemical (in particular physical and chemical) features of soil sediments within the landfill, which made it possible to assess the protective properties of soils in relation to the impact of technogenic metals. The condition of surface waters (ponds within the landfill territory) and groundwater (wells in Pidhirtsi village) was also studied; the comparison of the main indicators of chemical composition with the maximum allowable concentrations determined by normative documents was performed. It was found that in the studied soils there is a high concentration of heavy metals associated with the fraction of easily exchangeable ions, as well as an increased content of water-soluble forms. The main migration forms of macro- and microelements in soil solutions have been established. It was found that free hydrated cations and metal-organic complexes are characteristic of heavy metals. For groundwater used for potable water consumption by the population of Pidhirtsi village, exceeding of maximum allowable concentrations were recorded for certain indicators, in particular for nitrates, as well as deviations from the established norms for Ba, SO4, Fe, Mn, Co, Ni, Mo, and Pb. The pond waters, located directly within the landfill territory, are characterized by significant deviations from the norm in terms of Fe, Mn, Ni, Ti, V, Cu and Zn. As a result of the study, it was found that within the landfill there are favorable conditions for the formation of mobile forms of toxic elements and their migration to surface and groundwater
The article considers the relevance of the application of a set of terrestrial hydrological, radioecological and modern remote sensing methods in the process of monitoring studies of areas that are difficult to access, waterlogged, largely radionuclide contaminated. The example of the Ukrainian part of the left-bank Pripyat drainage system within the Chornobyl Exclusion Zone shows that remotely obtained data together with the materials integrated into the geographic information systems of the terrestrial measurements provide the adequate monitoring information on the spatio-temporal changes in the hydrological and radioecological situation in general. Among the research methods, the simulation, the methods of hydrometric, balancing, remote sensing studies of water bodies were most used. The main purpose of the research is to perform the retrospective and current analyses of the hydrological situation based on archival and recent satellite images, assess the effectiveness of the water protection complex on the left bank of the Pripyat River, especially after the introduction of hydrotechnical measures to improve its radioecological status. In the research process the LANDSAT, SPOT, IRS, WorldView images were used. In particular, a significant sensitivity of the "surface water – dry land" system to the changes in the environment of this area was established and the mapping of objects of open water surface was performed as well as its spatial and temporal variability was followed. When comparing the results of calculations of the radionuclides carry-over by water (in particular, 90Sr) before and after the implementation of appropriate measures at the water protection complex the notable negative consequences of its implementation and operation during a period from 1986 to 2001 were revealed. It was found that the diverted one-time 90Sr carry-over due to the construction of a "new" left-bank dam (according to the 1999 flood scenario) is "compensated" by 40% through the increase of its carry-over prolonged in time as a result of operation of the polder pumping station (PPS) and the inundation of the contaminated areas, which is caused by the complicated conditions for the discharge of surface and underground runoff caused by the "new" and "old" dams. The ecological advisability and validity of hydraulic measures (clearing of canals, reconstruction of culverts) and the recommended form of the operational complex (without the use of PPS, with natural filtration discharge of the body of the "new" sand dam in the Pripyat River) are confirmed by the results of thematic interpretation of the multiband images. Thus, within the complex, minor flooding and waterlogging of the inter-dam section, as well as areas to the north-east from the "old" dam are established. Prospects for the further research of various hydrological processes and radioecological situation on the left bank of the Pripyat River are seen in the use of high resolution remote surveys, which would be performed over the short periods of time. The informative result in good quality can be obtained on the basis of the use of unmanned aerial vehicles technology.
As a case study of the Piatyhorivka area of the Dnieper-Donets Depression with a level terrain is given to characterize the technology of computerized processing and structural identification of multiband remote sensing data. Its application enables to visualize the components of the terrestrial landscape for the research area more clearly. Moreover, as a result the identification of elements of a weakly incised (low-amplitude) erosion network, the differentiation of soils by spectral features, etc. became possible. On the basis of a combined analysis of a complex of landscape components, the structural interpretation of remote sensing data together with a priori data of geological and geophysical studies, the elements of the fault-block structure of the research area were refined. The zones of tectonic activation at the current stage of the development of the earth's crust were found within its limits.
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