PA6 and PMMA polymers with different MWCNTs addition (5, 7 and 9 wt %) were synthetized through casting solution, resulting in improvement properties in contrast to pristine polymers. SEM images showed the MWCNTs embedded into polymeric matrices. D, G and G´ bands of MWCNTs were confirmed by Raman spectroscopy and functional groups observed in both nanocomposites by FTIR demonstrated a strong interaction. A significant increasing in electrical conductivity and microhardness was observed in all the nanocomposites. Major microhardness values were obtained in MWCNTs/PA6 (50 HV) however the MWCNTs/PMMA nanocomposites showed the highest electrical conductivity value (6.4×10-4 S/cm).
Pseudoboehmite nanoparticles synthesized through the desulfation of Al2(SO4)3 were used to investigate the reinforcement of commercial porcelain stoneware. Fractured specimens investigated by SEM suggest that the added pseudoboehmite precursor generated a nanometric primary mullite phase dispersed in the porcelain glassy phase that limited and stopped the intergranular crack propagation. The porcelain modulus of rupture increased twice the value of the modulus of rupture (108 MPa) as compared with that samples without pseudoboehmite additions. Pseudoboehmite also led to increased densification of porcelain stoneware bodies up to 1250°C as shown by thermodilatometry data.
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