Photocapacitance measurements are reported on metal-insulator-semiconductor (MIS) capacitors employing polyimide (PI) or polysilsesquioxane (PSQ) as the gate insulator and poly(3-hexylthiophene) as the active semiconductor. By stressing devices into depletion while simultaneously irradiating with light of energy exceeding the semiconductor band gap, photogenerated electrons become trapped at the insulator/semiconductor interface or possibly in bulk insulator states. Additionally for the PSQ device, evidence is provided for the formation of a photogenerated inversion layer at the interface. The time dependence of electron detrapping in the PI case is similar to that observed for accumulation stress instability in organic MIS devices.
Compared to standard rotationally symmetric macroscopic optical components, free-form micro-optical arrays (FMOAs), sometimes termed microstructured optical surfaces, offer greater design freedom and a smaller footprint. Hence, they are used in optical devices to deliver new functionalities, enhanced device performance, and/or a greater degree of miniaturization. But their more complex surface shape is a challenge for traditional manufacturing technologies, and this has triggered a substantial effort by research institutes and industry to develop alternative fabrication solutions. Two-photon polymerization (2PP) is a promising additive manufacturing technology to manufacture 3D optical (micro)structures. The manufacturing times involved are, however, often impractically long, especially for the excellent surface quality required for optical applications. Recently, Nanoscribe GmbH has reduced manufacturing times substantially with the introduction of so-called two-photon grayscale lithography (2GL). However, its acceleration potential and consequent impact on surface quality have, to the best of our knowledge, yet to be reported. A direct comparison between 2PP and 2GL indicates that, for the investigated FMOA, 2GL is around five times faster than 2PP and also delivers better surface quality. This study therefore confirms the potential of 2GL to manufacture complexly shaped FMOAs.
Chiral metamaterials are widely used to implement devices that transform the polarization of an incident electromagnetic wave, such as polarization rotators and linear to circular converters, but rarely used as circular polarization converters. This letter presents a chiral metamaterial that changes the handedness of a circularly polarized incident wave. This structure, which presents subwavelength thickness, provides polarization conversion with independence on both the front and back directions and the handedness of the incident wave. High polarization conversion efficiency is shown by both simulations and experiments.
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