Visible to near‐IR (0.4–1.0 μm) spectral reflectance observations of Mars during the 1988 opposition were performed at Mauna Kea Observatory using a circular variable filter spectrometer at a spectral resolution R = λ/Δλ ≈ 80. On August 13 and 14 1988, UT, 41 regions 500–600 km in diameter were observed on Mars. The data have been reduced both to reflectance relative to solar analog (Mars/16 Cyg B) and to relative reflectance (spot/spot). The spectra show the strong near‐UV reflectance dropoff characteristic of Mars as well as absorptions at 0.62–0.72 μm and 0.81–0.94 μm both seen here clearly for the first time. These absorption features are interpreted as Fe3+ electronic transition bands that indicate the presence of crystalline ferric oxide or hydroxide minerals on the Martian surface. Comparison of these data with laboratory spectra obtained by other workers supports the conclusion that a single iron oxide phase, most likely hematite, could account for all of the observed spectral behavior of the Martian surface soils and airborne dust in the 0.4–1.0 μm region. This possibility must be reconciled with data from other possible spectral analogs and other wavelength regions as well as geochemical and mineral stability considerations to arrive at a more complete understanding of the role of ferric minerals in Martian surface mineralogy and weathering.

A positive identification of the minerals olivine, plagioclase, and several types of pyroxenes were made at several locations on the lunar surface by using remote measurements. For example, the crater Aristarchus is found to have an average pyroxene composition of augite, and plagioclase is obviously present. A dark mantle deposit in the crater J. Herschel is at least partly composed of a mixture of 70% olivine and 30% pyroxene. These determinations were possible because the reflectance spectra for 10–20 km diameter lunar areas have been measured for the first time in the IR spectral region (0.65–2.5 μm) with sufficient spectral resolution and photometric precision to define mineral electronic absorption bands. The reflectance for all lunar regions observed (over 100 to present) continues to increase toward longer wavelengths to at least 2.5 μm, and several mineral absorption bands appear. The telescopic spectra are of similar quality and contain features similar to laboratory spectra of lunar samples. The absorption features in several spectra have been quantitatively analyzed using newly developed computer processing techniques, including thermal flux removal and absorption band fitting, to produce these mineral identifications. Detection and quantitative analysis of these absorptions provide a much improved basis for remotely determining and mapping surface mineralogy quantitatively from the ground or using airborne or spacecraft platforms.

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