Although the vast majority of high-Tc cuprate superconductors are hole-doped, a small family of electron-doped compounds exists. Under investigated until recently, there has been tremendous recent progress in their characterization. A consistent view is being reached on a number of formerly contentious issues, such as their order parameter symmetry, phase diagram, and normal state electronic structure. Many other aspects have been revealed exhibiting both their similarities and differences with the hole-doped compounds. This review summarizes the current experimental status of these materials. We attempt to synthesize this information into a consistent view on a number of topics important to both this material class as well as the overall cuprate phenomenology including the phase diagram, the superconducting order parameter symmetry, electron-phonon coupling, phase separation, the nature of the normal state, the role of competing orders, the spin-density wave mean-field description of the normal state, and pseudogap effects.

Angle-resolved photoemission experiments reveal evidence of an energy gap in the normal state excitation spectrum of the cuprate superconductor Bi2Sr2CaCu2O8+delta. This gap exists only in underdoped samples and closes around the doping level at which the superconducting transition temperature Tc is a maximum. The momentum dependence and magnitude of the gap closely resemble those of the dx2-y2 gap observed in the superconducting state. This observation is consistent with results from several other experimental techniques, which also indicate the presence of a gap in the normal state. Some possible theoretical explanations for this effect are reviewed.

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The perfectly linear temperature dependence of the electrical resistivity observed as T → 0 in a variety of metals close to a quantum critical point 1,2,3,4 is a major puzzle of condensed matter physics 5 . Here we show that T-linear resistivity as T → 0 is a generic property of cuprates, associated with a universal scattering rate. We measured the low-temperature resistivity of the bi-layer cuprate Bi2Sr2CaCu2O8+δ and found that it exhibits a T-linear dependence with the same slope as in the single-layer cuprates Bi2Sr2CuO6+δ (ref. 6), La1.6-xNd0.4SrxCuO4 (ref. 7) and La2-xSrxCuO4 (ref. 8), despite their very different Fermi surfaces and structural, superconducting and magnetic properties.We then show that the T-linear coefficient (per CuO2 plane), A1 ☐ , is given by the universal relation A1 ☐ TF = h / 2e 2 , where e is the electron charge, h is the Planck constant and TF is the Fermi temperature. This relation, obtained by assuming that the scattering rate 1 / τ of charge carriers reaches the Planckian limit 9,10 , whereby ħ / τ = kB T, works not only for hole-doped cuprates 6,7,8,11,12 but also for electrondoped cuprates 13,14 , despite the different nature of their quantum critical point and strength of their electron correlations.