The absence of simple examples of superconductivity adjoining itinerant-electron ferromagnetism in the phase diagram has for many years cast doubt on the validity of conventional models of magnetically mediated superconductivity. On closer examination, however, very few systems have been studied in the extreme conditions of purity, proximity to the ferromagnetic state and very low temperatures required to test the theory definitively. Here we report the observation of superconductivity on the border of ferromagnetism in a pure system, UGe2, which is known to be qualitatively similar to the classic d-electron ferromagnets. The superconductivity that we observe below 1 K, in a limited pressure range on the border of ferromagnetism, seems to arise from the same electrons that produce band magnetism. In this case, superconductivity is most naturally understood in terms of magnetic as opposed to lattice interactions, and by a spin-triplet rather than the spin-singlet pairing normally associated with nearly antiferromagnetic metals.
We report the observation of heavy-fermion superconductivity in CeCoIn 5 at T c = 2.3 K. When compared to the pressure-induced T c of its cubic relative CeIn 3 (T c ∼ 200 mK), the T c of CeCoIn 5 is remarkably high. We suggest that this difference may arise from magnetically mediated superconductivity in the layered crystal structure of CeCoIn 5. Superconductivity is distinct in the correlation often evident between structure and properties: certain crystal structures or substructures favour superconductivity [1]. In particular, what underlies this relationship in the high-T c cuprates and heavy-fermion materials, which border so closely on magnetically ordered phases, is of essential interest both fundamentally and in the search for new superconducting materials [2, 3]. For example, fully half of the known heavyfermion superconductors crystallize in the tetragonal ThCr 2 Si 2 structure, which is also the structure type of the La 2 CuO 4 family of high-T c superconductors [4]. For the cuprates, there is no consensus on the origin of the superconductivity, but their quasi-2D structure and proximity to magnetic order have been shown to be particularly favourable for an unconventional form of superconductivity in which a pairwise-attractive interaction among quasiparticles is mediated by magnetic correlations [5]. Here, we report the discovery of a possible heavy-fermion analogue of the cuprates, a new layered superconductor CeCoIn 5 , with the highest known ambient-pressure superconducting transition temperature T c in the class of heavy-fermion materials. Heavy-fermion superconductors are materials in which superconductivity emerges out of a normal state with strong electronic correlations. The presence of an appropriate magnetic ion-in this case Ce-enhances the effective mass m * of conduction electrons by several orders of magnitude [6]. In the more than twenty years since the first heavy-fermion superconductor was discovered (CeCu 2 Si 2) [7], only one other Ce-based material has been found that unambiguously shows superconductivity at ambient pressure: CeIrIn 5 [8]. Both of these materials exhibit rather complex phenomena and/or metallurgy, making their study challenging. The ground state of CeCu 2 Si 2 can be either antiferromagnetic or superconducting depending on very small changes in unit-cell volume or composition [9]; CeIrIn 5 shows zero resistivity near 1 K but does not produce a thermodynamic signature of superconductivity until
The idea of superconductivity without the mediating role of lattice vibrations (phonons) has a long history. It was realized soon after the publication of the Bardeen-Cooper-Schrieffer (BCS) theory of superconductivity 50 years ago that a full treatment of both the charge and spin degrees of freedom of the electron predicts the existence of attractive components of the effective interaction between electrons even in the absence of lattice vibrations--a particular example is the effective interaction that depends on the relative spins of the electrons. Such attraction without phonons can lead to electronic pairing and to unconventional forms of superconductivity that can be much more sensitive than traditional (BCS) superconductivity to the precise details of the crystal structure and to the electronic and magnetic properties of a material.
We show that the retarded interaction between quasiparticles on a 2D square lattice induced by the exchange of antiferromagnetic paramagnons leads uniquely to a transition to a superconducting state with d,. 2,2 symmetry. With a spin-excitation spectrum and a quasiparticle-paramagnon coupling determined by fits to normal-state experiments, we obtain high transition temperatures and energy-gap behaviors comparable to those measured for YBa2Cu307, YBa2Cu30663, and Lal~qSr() I~Cu04.
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