High-entropy ceramics (HECs) have attracted much attention due to their huge composition space, unique microstructure, and desirable properties. In contrast to previous studies, which have primarily focused on HECs with one anion, herein, we report a new family of ceramics with both multi-cationic and-anionic structures, i.e., high-entropy carbide-nitrides (Ti 0.33 Zr 0.33 Hf 0.33)(C 0.5 N 0.5), (Ti 0.25 Zr 0.25 Hf 0.25-Nb 0.25)(C 0.5 N 0.5) and (Ti 0.2 Zr 0.2 Hf 0.2 Nb 0.2 Ta 0.2)(C 0.5 N 0.5). These as-synthesized HECs are mainly comprised of a face-centered cubic solid-solution phase accompanied by minor inevitable oxide phases. The formation mechanism of the solid-solution phase is discussed in terms of the lattice size difference and thermodynamic competition between configurational entropy and mixing enthalpy. It is found that the increment in the configurational entropy can effectively lower the sintering temperature and increase the fracture toughness. Particularly, the newly developed (Ti 0.2 Zr 0.2 Hf 0.2 Nb 0.2 Ta 0.2)(C 0.5 N 0.5) exhibits a decent fracture toughness of 8.4 MPa m 1/2 and a low sintering temperature of 1750°C, making it promising for ultra-high temperature applications. Our work not only enriches knowledge regarding the HECs categories, but also opens a new pathway for developing HECs with multi-cationic and-anionic structures.

The effect of light burned magnesia on the performance of sleeve grouting under different content gradients was studied. The results show that the light burnt magnesia content has no significant effect on the fluidity of the grout when it is less than 5%. The incorporation of light burned magnesia improves the compressive strength of the sleeve grout and the expansion rate of 14d∼56d in restrict condition. The incorporation of light burned magnesia can effectively solve the problem of shrinkage of the grouted slurry volume in the later stage and improve the compressive strength of the sleeve grout.