In this study, localized surface plasmon resonance mediated by aluminium nanoparticles (Al NPs) was employed to enhance the ultraviolet (UV) response of ZnO nanorod array (NRA) photodetectors grown vertically on a Quartz substrate using a simple vapor transport method. The responsivity of the ZnO NRA photodetector decorated with Al NPs was enhanced from 0.12 to 1.59 A W(-1) and the sensitivity and response rate have been improved greatly compared with those of the bare one. The measurement results in the transmittance spectra and time-resolved photoluminescence spectra suggest that the improved photoresponse and the enhanced spontaneous emission of the ZnO NRA photodetector with Al NP decoration are both attributed to resonant coupling between the excitons in ZnO and the localized surface plasmons (LSPs) in the Al NPs. Our results demonstrated that the plasmon-enhanced ZnO NRA photodetector has a great potential for application in building sensors with a fast response and reset time, high sensitivity, and good signal-to-noise ratio for photoelectric sensing.
Radix Astragali (RA) is one of the commonly-used traditional Chinese medicines (TCMs) with an immunomodulatory effect confirmed in the clinic. In order to better understand the material basis for the therapeutic effects, this study was to investigate the absorbed components and their pharmacokinetic profile after oral administration of RA on cyclophosphamide-induced immunosuppression in Balb/c mice. As a result, 51 compounds in RA extract and 31 prototype compounds with nine metabolites were detected in mice plasma by the ultra-fast liquid chromatography (UFLC)-DAD-Q-TOF-MS/MS method. The pharmacokinetic parameters of five main constituents, including calycosin-7-O-glucoside, ononin, calycosin, formononetin and astragaloside IV, were obtained using HPLC-MS/MS. These results offered useful information for research on the pharmacological mechanism of RA and for its further development.
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