A study on the functionalization of cotton and viscose fabrics to achieve bifunctional conductive and antibacterial properties was carried out; 0.5 wt% AgNW ethanolic colloid was prepared, and fabrics were dipped and dried in the colloid 1, 10 and 15 times. After one dipping, both fabrics remained nonconductive, and the surface resistance (R s ) of cotton was 4.9 9 10 10 and of viscose 3.6 9 10 11 X. Excellent conductivity properties were shown in cotton fabric after 10 dippings (20 X) and in viscose fabric after 15 dippings (46 X). The Ag content of these fabrics was 53.3 and 52.3% (SEM/EDX analysis) and 13.77 and 14.12% (TG/DTG analysis) for cotton and viscose, respectively. XRD analysis revealed the presence of AgNWs on the fabric surface. FTIR/ATR, Raman and TG analysis confirmed the effects of modifications. The AgNW layers on both fabric surfaces were resistant to abrasion. After 50 washes of the modified cotton fabric, R s increased from 20 to 195 X. The AgNW layer was stable and the fabric still highly conductive. However, viscose fabric became nonconductive after two washes, and the surface resistance increased from 46 to 1.4 9 10 11 X. The tensile strength of cotton modified with AgNWs increased by about 49% and for viscose decreased by about 27%. AgNW-modified cotton fabric showed a significant antibacterial effect against S. aureus and K. pneumoniae bacteria. The presented method is more suitable for cotton because the modified cotton fabric retains the mechanical and conductive properties even after many washes.
The method of TiO 2 -anatase film preparation on cotton and viscose fabric surfaces using the sol-gel process and microwave treatment is presented. Microwave treatment was used to change the amorphous TiO 2 form to anatase directly on the fabrics. The influence of microwave treatment conditions on the obtainable polymorphic form of TiO 2 was examined. Fabrics were pretreated with low-temperature air plasma (30 min). The root mean square height in the selected area increased from 44 to 166 nm (cotton) and from 9 to 112 nm (viscose). Infrared analysis showed the new band at 1748 and 1732 cm -1 corresponding to C=O stretching for plasma-treated cotton and viscose textiles, respectively. The plasma pretreatment also improved the wetting properties by TiO 2 sol and increased the surface free energy of fabrics. TiO 2 film thickness was 180 nm (12 %wg. Ti) and 140 nm (3 %wg. Ti) for cotton and viscose, respectively. TiO 2 -modified cotton reduced the nicotine concentration three times more and TiO 2 -modified viscose was two times higher under sunlight compared to raw fabrics. No changes in strength were observed for TiO 2 -modified cotton, while the strength of TiO 2 -modified viscose decreased about 45 %. No effect of UV irradiation on cotton and a slight reduction of the strength of raw viscose (7 %) and TiO 2 -modified viscose (16 %) were observed. The Ti contents after washing decreased from 12 to 11 % (cotton) and from 3 to 2.6 % (viscose). The presented method allows obtaining TiO 2 film-anatase on the cotton and viscose fabrics, but its total effectiveness is better for cotton fabrics.
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