Dye wastes represent one of the most problematic groups of pollutants because they can be easily identified by the human eye and are not easily biodegradable. This literature review paper highlights and provides an overview of dye waste treatments performed over the three years period from 2008-2010. Noteworthy processes for the treatment of dye waste include biological treatment, catalytic oxidation, filtration, sorption process and combination treatments.
Lipase-catalyzed production of palm esters by alcoholysis of palm oil with oleyl alcohol in n-hexane was performed in 2L stirred-tank reactor (STR). Investigation on the performance of reactor operation was carried out in batch mode STR with single impeller mounted on the centrally located shaft. Rushton turbine (RT) impellers provide the highest reaction yield (95.8%) at lower agitation speed as compared to AL-hydrofoil (AL-H) and 2-bladed elephant ear (EE) impellers. Homogenous enzyme particles suspension was obtained at 250 rpm by using RT impeller. At higher impeller speed, the shear effect on the enzyme particles caused by agitation has decreased the reaction performance. Palm esters reaction mixture in STR follows Newtons' law due to the linear relation between the shear stress (tau) and shear rate (dupsilon/dy). High stability of Lipozyme RM IM was observed as shown by its ability to be repeatedly used to give high percentage yield (79%) of palm esters even after 15 cycles of reaction. The process was successfully scale-up to 75 L STR (50 L working volume) based on a constant impeller tip speed approach, which gave the yield of 97.2% after 5h reaction time.
The rapid growth of the human population and industrialization in the world has indirectly increased environmental problems such as water, air and land pollution. Amongst all, heavy metals can be considered as the most problematic pollutants. Numerous efforts have been attempted to minimize the impact of heavy metals. This chapter discusses the recent developments and technical applicability of different treatment methods for heavy metal removal. The adsorption process using various lowcost materials as the potential alternative for heavy metal removal is being highlighted and summarized.
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