Processes controlling the composition of seafloor hydrothermal fluids in silicic back-arc or neararc crustal settings remain poorly constrained despite growing evidence for extensive magmatichydrothermal activity in such environments. We conducted a survey of vent fluid compositions from two contrasting sites in the Manus back-arc basin, Papua New Guinea, to examine the influence of variations in host rock composition and magmatic inputs (both a function of arc proximity) on hydrothermal fluid chemistry. Fluid samples were collected from felsic-hosted hydrothermal vent fields located on Pual Ridge (PACMANUS and Northeast (NE) Pual) near the active New Britain Arc and a basalt-hosted vent field (Vienna Woods) located farther from the arc on the Manus Spreading Center. Vienna Woods fluids were characterized by relatively uniform endmember temperatures (273-285°C) and major element compositions, low dissolved CO 2 concentrations (4.4mmol/kg) and high measured pH (4.2-4.9 at 25°C).Temperatures and compositions were highly variable at PACMANUS/NE Pual and a large, newly discovered vent area (Fenway) was observed to be vigorously venting boiling (358°C) fluid. All 2

Oceanic plateaus form by mantle processes distinct from those forming oceanic crust at divergent plate boundaries. Eleven drillsites into igneous basement of Kerguelen Plateau and Broken Ridge, including seven from the recent Ocean Drilling Program Leg 183 (1998^99) and four from Legs 119 and 120 (1987^88), show that the dominant rocks are basalts with geochemical characteristics distinct from those of mid-ocean ridge basalts. Moreover, the physical characteristics of the lava flows and the presence of wood fragments, charcoal, pollen, spores and seeds in the shallow water sediments overlying the igneous basement show that the growth rate of the plateau was sufficient to form subaerial landmasses. Most of the southern Kerguelen Plateau formed at V110 Ma, but the uppermost submarine lavas in the northern Kerguelen Plateau erupted during Cenozoic time. These results are consistent with derivation of the plateau by partial melting of the Kerguelen plume. Leg 183 provided two new major observations about the final growth stages of the Kerguelen Plateau. 1: At several locations, volcanism ended with explosive eruptions of volatilerich, felsic magmas; although the total volume of felsic volcanic rocks is poorly constrained, the explosive nature of the eruptions may have resulted in globally significant effects on climate and atmospheric chemistry during the late-stage, subaerial growth of the Kerguelen Plateau. 2: At one drillsite, clasts of garnet^biotite gneiss, a continental rock, occur in a fluvial conglomerate intercalated within basaltic flows. Previously, geochemical and geophysical evidence has been used to infer continental lithospheric components within this large igneous province. A continental geochemical signature in an oceanic setting may represent deeply recycled crust incorporated into the Kerguelen plume or continental fragments dispersed during initial formation of the Indian Ocean during breakup of Gondwana. The clasts of garnet^biotite gneiss are the first unequivocal evidence of continental crust in this oceanic plateau. We propose that during initial breakup between India and Antarctica, the spreading center jumped northwards transferring slivers of the continental Indian plate to oceanic portions of the Antarctic plate. ß

No abstract

The SuSu Knolls and DESMOS hydrothermal fields are located in the back-arc extensional transform zone of the Eastern Manus Basin. In 2006, highly acidic and RSO 4 -rich vent fluids were collected at both sites and analyzed for the chemical and isotopic composition of major and trace species. Fluids exiting the seafloor have measured temperatures from 48 to 215°C and are milky white in appearance due to precipitation of elemental S 0 . Vent fluid concentrations of Na, K, and Mg are depleted by as much as 30% relative to seawater, but have the same relative abundance. In contrast, the fluids are highly enriched in dissolved RCO 2 , Cl, SiO 2(aq) , Fe, and Al relative to seawater. Measured pH (25°C) ranged from 0.95 to 1.87 and aqueous RSO 4 ranged from 35 to 135 mmol/kg. The chemical and isotopic composition points to formation via subsurface mixing of seawater with a Na-, K-, Mg-, and Ca-free, volatile-rich magmatic fluid exsolved from subsurface magma bodies during a process analogous to subaerial fumarole discharge. Estimates of the magmatic end-member composition indicate a fluid phase where H 2 O > SO 2 > CO 2 % Cl > F. The hydrogen and oxygen isotopic composition of H 2 O and carbon isotopic composition of RCO 2 in the vent fluids strongly suggest a contribution of slab-derived H 2 O and CO 2 to melts generated in the mantle beneath the Eastern Manus volcanic zone. Abundant magmatically-derived SO 2 undergoes disproportionation during cooling in upflow zones and contributes abundant acidity, SO 4 2À , and S 0 to the venting fluids. Interaction of these highly acidic fluids with highly altered mineral assemblages in the upflow zone are responsible for extensive aqueous mobilization of SiO 2(aq), Fe, and Al. Temporal variability in the speciation and abundance of aqueous S species between 1995 and 2006 at the DESMOS vent field suggests an increase in the relative abundance of SO 2 in the magmatic end-member that has mixed with seawater in the subsurface. Results of this study constrain processes responsible for the formation of hot-spring fluids in magmatically active back-arc environments and the resulting chemical exchange between the lithosphere and water column.

Oxygen and hydrogen isotope fractionation factors in the talc-water and serpentine-water systems have been determined by laboratory experiment from 250 to 450°C at 50 MPa using the partial exchange technique. Talc was synthesized from brucite + quartz, resulting in nearly 100%