Ward has communicated to us privately that he has also observed an enhancement factor greater than 650 for chloroform formation.(7) G. Gloss, J. Amer. Chem. Soc., 91, 4552 (1969). This model has since been extended to cover energy polarization: G. L. Gloss, private communication.
S.ummaryThe preparation of several transition-metal cyanotrihydroborate complexes is reported and their physical properties are shown to be consistent with an M-NCBH, type structure.
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