The statistical mechanics of particles with shapes on a one-dimensional lattice is investigated in the context of the s = 1 Ising chain with uniform nearest-neighbor coupling, quadratic single-site potential, and a magnetic field, which supports four distinct ground states:The complete spectrum is generated from each ground state by particles from a different set of six or seven species. Particles and elements of the pseudovacuum are characterized by motifs (patterns of several consecutive site variables). Particles are floating objects that can be placed into open slots on the lattice. Open slots are recognized as permissible links between motifs. The energy of a particle varies between species but is independent of where it is placed. Placement of one particle changes the open-slot configuration for particles of all species. This statistical interaction is encoded in a generalized Pauli principle, from which the multiplicity of states for a given particle combination is determined and used for the exact statistical mechanical analysis. Particles from all species belong to one of four categories: compacts, hosts, tags, or hybrids. Compacts and hosts find open slots in segments of pseudovacuum. Tags find open slots inside hosts. Hybrids are tags with hosting capability. In the taxonomy of particles proposed here, "species" is indicative of structure and "category" indicative of function. The hosting function splits the Pauli principle into exclusion and accommodation parts. Near phase boundaries, the state of the Ising chain at low temperature is akin to that of miscible or immiscible liquids with particles from one species acting as surfactant molecules.

Abstract. The exclusion statistics of two complementary sets of quasiparticles, generated from opposite ends of the spectrum, are identified for Ising chains with spin s = 1/2, 1. In the s = 1/2 case the two sets are antiferromagnetic domain walls (solitons) and ferromagnetic domains (strings). In the s = 1 case they are soliton pairs and nested strings, respectively. The Ising model is equivalent to a system of two species of solitons for s = 1/2 and to a system of six species of soliton pairs for s = 1. Solitons exist on single bonds but soliton pairs may be spread across many bonds. The thermodynamics of a system of domains spanning up to M lattice sites is amenable to exact analysis and shown to become equivalent, in the limit M → ∞, to the thermodynamics of the s = 1/2 Ising chain. A relation is presented between the solitons in the Ising limit and the spinons in the XX limit of the s = 1/2 XXZ chain.

The coordinate Bethe ansatz solutions of the XXZ model for a one-dimensional spin-1/2 chain are analyzed with focus on the statistical properties of the constituent quasiparticles. Emphasis is given to the special cases known as XX, XXX, and Ising models, where considerable simplifications occur. The XXZ spectrum can be generated from separate pseudovacua as configurations of sets of quasiparticles with different exclusion statistics. These sets are complementary in the sense that the pseudovacuum of one set contains the maximum number of particles from the other set. The Bethe ansatz string solutions of the XXX model evolve differently in the planar and axial regimes. In the Ising limit they become ferromagnetic domains with integer-valued exclusion statistics. In the XX limit they brake apart into hard-core bosons with (effectively) fermionic statistics. Two sets of quasiparticles with spin 1/2 and fractional statistics are distinguished, where one set (spinons) generates the XXZ spectrum from the unique, critical ground state realized in the planar regime, and the other set (solitons) generates the same spectrum from the twofold, antiferromagnetically ordered ground state realized in the axial regime. In the Ising limit, the solitons become antiferromagnetic domain walls.

The s = 1/2 Ising chain with uniform nearest-neighbor and next-nearest-neighbor coupling is used to construct a system of floating particles characterized by motifs of up to six consecutive local spins. The spin couplings cause the assembly of particles which, in turn, remain free of interaction energies even at high density. All microstates are configurations of particles from one of three different sets, excited from pseudo-vacua associated with ground states of periodicities one, two, and four. The motifs of particles and elements of pseudo-vacuum interlink in two shared site variables. The statistical interaction between particles is encoded in a generalized Pauli principle, describing how the placement of one particle modifies the options for placing further particles. In the statistical mechanical analysis arbitrary energies can be assigned to all particle species. The entropy is a function of the particle populations. The statistical interaction specifications are transparently built into that expression. The energies and structures of the particles alone govern the ordering at low temperature. Under special circumstances the particles can be replaced by more fundamental particles with shorter motifs that interlink in only one shared site variable. Structures emerge from interactions on two levels: particles with shapes from coupled spins and long-range ordering tendencies from statistically interacting particles with shapes.

This work introduces a methodology for the statistical mechanical analysis of polymeric chains under tension controlled by optical or magnetic tweezers at thermal equilibrium with an embedding fluid medium. The response of single bonds between monomers or of entire groups of monomers to tension is governed by the activation of statistically interacting particles representing quanta of extension or contraction. This method of analysis is capable of describing thermal unbending of the freely-jointed or worm-like chain kind, linear or nonlinear contour elasticity, and structural transformations including effects of cooperativity. The versatility of this approach is demonstrated in an application to double-stranded DNA undergoing torsionally unconstrained stretching across three regimes of mechanical response including an overstretching transition. The three-regime forceextension characteristic, derived from a single free-energy expression, accurately matches empirical evidence. (c) J τ J J (b) (d) (a) FIG. 1: (Color online) Schematic representations for a chain of N = 7 monomers of (a) the reference state, (b) a state under tension with extension particles activated, (c) a state under tension and torque with twist-contraction particles activated, and (d) a state under tension with extension particles and contact particles activated.