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Flow mapping and physical volcanology of 15 basaltic lavas exposed in three critical road pass sections (ghats) in the Koyna-Warna region of the western Deccan Traps is presented in this paper. Transitional lavas like rubbly pahoehoe are most common morpho-type exposed in these ghat sections. Sinking of rubbly breccia into flow interiors and formation of breccia-cored rosette are common in some lava flows. Few rubbly lavas exhibit slabby tendencies. The amount and nature of the associated rubble is variable and result from the mechanical fracturing and auto-brecciation of the upper vesicular crust in response to distinctive stages in the cooling, crystallization and emplacement history of individual lava flows. Occurrence of aa and pahoehoe morpho-types in the lava flow sequence is subordinate. Three prominent pahoehoe flows separated by red bole horizons are seen in the upper parts of the Kumbharli ghat. These are thick, P-type sheet pahoehoe. The pahoehoe lavas represent compound flow fields that grew by budding, endogenous lava transfer and inflation. Presence of pahoehoe lavas in the Koyna-Warna region hints at possible hitherto unrecorded southern extension of Bushe-like flow fields. This study reconfirms the existence of pahoehoe-slabby-rubbly-aa flow fields and transitions even in the upper echelons of the Deccan Trap stratigraphy. The study of morphology and internal structure of lava flows exposed at the ghat sections in the Koyna-Warna region could guide sub-surface core-logging that is critical in deciphering the physical volcanology and emplacement dynamics of basaltic lava flows penetrated by drill holes sunk under the scientific deep drilling programme.

The development of Schiff base was a major step forward in the area of coordination chemistry. Schiff bases, a class of organic compounds, carry the imine or azomethine (>C=N–) functional group. Schiff bases played an influencing role in the development of coordination chemistry and were a key point in the development of inorganic, bioinorganic chemistry and optical materials. Schiff bases, widely used in inorganic, organic, and analytical chemistry, account for a significant portion of the more commonly employed classes of organic molecules. The ability of Schiff base ligands to form stable metal complexes with a wide range of transition and other metal ions makes them extremely useful. Condensation of a primary amine with an aldehyde or ketone yields a Schiff bases. In this chapter, we focused on introducing Schiff bases, classified them and their metal complexes, and discussed several synthesis methods, including conventional and green approaches. This chapter also elaborated on the industries’ applications, such as the food industry, agrochemical industry, dye industry, analytical chemistry, catalysis, energy storage, environmental, chemo-sensing, bio-sensing, and biomedical applications of novel Schiff bases and their metal complexes.

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