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In order to study the influence characteristics of water bath at different temperatures on rock physical and dynamic mechanical properties, a total of 15 groups of temperature-water bath treatment were carried out on coal mine roadway sandstone at 25°C∼95°C, and the basic physical parameters were tested. The impact compression test was carried out using the split Hopkinson pressure bar (SHPB) device. The results show that, with the increase of water bath temperature, the particle gap on the specimen surface increases. The volume, mass, and density of the specimens all increased with the increase of water bath temperature, and the increase was closely related to the water bath temperature. The dynamic compressive strength increases as a quadratic function of the water bath temperature, and the rate of increase is different before and after 45°C. The dynamic peak strain and average strain rate showed a quadratic function with the water bath temperature. The dynamic peak strain before 45°C decreased with the temperature increasing, and the dynamic peak strain after 45°C increased with the temperature increasing. The dynamic elastic modulus increased first and then decreased with the increase of water bath temperature and reached the maximum at 45°C. The failure pattern of sandstone is spalling. With the increase of water bath temperature, the fracture degree of the specimen gradually decreases.

A new electrochemical immunosensor for serum myeloperoxidase (MPO) has been developed based on the self-assembly multilays of multi-walled carbon nanotubes (MWNTs), thionine (THI), gold nanoparticles (GNPs) and chitosanon (CHIT) on the glassy carbon electrode (GCE). The antibody of MPO (anti-MPO) was absorbed on the surface of GNPs monolayer. Horseradish peroxidase (HRP) was employed to block non-specific binding and amplify the response current signal. It was observed that the peak current was linear with the MPO concentration in a range of 2.5-125 µgl-1. The detection limit was 1.425 µgl-1 (S/N=3). Correlation analysis showed that this new immunosensor assay has a significant correlation with enzyme-linked immunosorbent assay (ELISA) (r=0.96, p>0.05) for 40 clinical specimens.